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Merck

703206

Sigma-Aldrich

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II)

Sinónimos:

Greatcell Solar®, N-3 dye

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About This Item

Fórmula empírica (notación de Hill):
C26H16N6O8RuS2
Número de CAS:
Peso molecular:
705.64
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

assay

95% (NMR)

Quality Level

form

powder

mp

>300 °C

λmax

534, 395, 312 nm (lit.)

SMILES string

S=C=N[Ru]N=C=S.OC(=O)c1ccnc(c1)-c2cc(ccn2)C(O)=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C(O)=O

InChI

1S/2C12H8N2O4.2CNS.Ru/c2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

InChI key

VMISXESAJBVFNH-UHFFFAOYSA-N

General description

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) (N3 dye) is a ruthenium polypyridyl based complex that can be used as a sensitizer. It is a highly stable polymer in which the photocurrent decreases with an increase in the concentration of N3 dye.

Application

N3 dye can be coated on electrodes for improving the sensitivity of the dye sensitized solar cells (DSSCs) which can further enhance the power conversion efficiency (PCE).

Legal Information

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Dyesol is a registered trademark of Greatcell Solar

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Visite la Librería de documentos

Ruthenium (II) Charge-Transfer Sensitizers Containing 4, 4 `-Dicarboxy-2, 2 `-bipyridine. Synthesis, Properties, and Bonding Mode of Coordinated Thio-and Selenocyanates
Kohle O, et al.
Inorganic Chemistry, 35(16), 4779-4787 (1996)
Determination of the electron lifetime in nanocrystalline dye solar cells by open-circuit voltage decay measurements
Zaban A, et al.
ChemPhysChem, 4(8), 859-864 (2003)
Stark effects after excited-state interfacial electron transfer at sensitized TiO2 nanocrystallites
Ardo S, et al.
Journal of the American Chemical Society, 132(19), 6696-6709 (2010)
Transport-limited recombination of photocarriers in dye-sensitized nanocrystalline TiO2 solar cells
Kopidakis N, et al.
The Journal of Physical Chemistry B, 107(41), 11307-11315 (2003)
On the role of metal contacts in solar cells based on titanium dioxide and di-(isothiocyanate)-bis-(2, 2'-bipyridyl-4, 4'-dicarboxylate) ruthenium (II)
Logunov AA, et al.
Semiconductors, 48(5), 683-685 (2014)

Artículos

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Dye-sensitized solar cells (DSSCs) attract attention for high performance and potential low-cost production in solar energy.

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