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Merck

669431

Sigma-Aldrich

Lithium fluoride

Precipitated, 99.995%

Sinónimos:

Fluorolithium

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About This Item

Fórmula lineal:
LiF
Número de CAS:
Peso molecular:
25.94
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.995%

form

powder

impurities

≤55.0 ppm Trace Metal Analysis

mp

845 °C (lit.)

density

2.64 g/mL at 25 °C (lit.)

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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General description

Lithium fluoride is an inorganic halide with good ionic conductivity, high refractive index, and high transmittance in the UV region. Owing to its unique properties, it is widely used in the field of optical and electronic devices, X-ray imaging, and dental materials.

Application

Lithium fluoride(LiF) can be used:
  • To fabricate an insulating layer in AC-driven organic light-emitting diodes(OLEDs). LiF provides excellent capacitance and high stability to the insulating layers in AC devices.
  • As a precursor to synthesize Eu2+/Ce3+ doped barium lithium fluoride phosphors by solvothermal method.
  • To fabricate LiF thin film coating on the lithium anodes to enhance their stability and coulombic efficiency.
  • As an additive to enrich and enhance the performance of solidelectrolyte interface(SEI) in Li metal batteries.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Novel ALD Chemistry Enabled Low-Temperature Synthesis of Lithium Fluoride Coatings for Durable Lithium Anodes
Lin Chen, et al.
ACS Applied Materials & Interfaces, 10, 26972-26981 (2018)
Solvothermal fabrication and luminescent properties of Eu2+/Ce3+ doped barium lithium fluoride
Guoxian ZHU, et al.
Journal of Rare Earths, 30, 985-989 (2012)
The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium
Mingfu He, et al.
Proceedings of the National Academy of Sciences, 117, 73-79 (2020)
Alternating current driven organic light emitting diodes using lithium fluoride insulating layers
Shang-Yi Liu, et al.
Scientific Reports, 4, 7559-7559 (2014)
Thorsten Grünheid et al.
American journal of orthodontics and dentofacial orthopedics : official publication of the American Association of Orthodontists, its constituent societies, and the American Board of Orthodontics, 141(4), 436-443 (2012-04-03)
Cone-beam computed tomography (CBCT) has become a routine imaging modality for many orthodontic clinics. However, questions remain about the amount of radiation patients are exposed to during the scans. This study determined the amounts of radiation potentially absorbed by a

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