667854

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane

kanata purity

• Sinónimos: (S,S)-Ph-BPE,BPE
• Fórmula empírica (notación de Hill): C₃₄H₃₆P₂
• Número de CAS: 824395-67-7
• Peso molecular: 506.60
• MDL number: MFCD07369028
• UNSPSC Code: 12352005
• PubChem Substance ID: 24884945
• NACRES: NA.22

Propiedades

• Quality Level: 100
• form: solid
• mp: 143-147 °C
• SMILES string: C1C[C@H](P(CCP2[C@@H](CC[C@H]2c3ccccc3)c4ccccc4)[C@@H]1c5ccccc5)c6ccccc6
• InChI: 1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m0/s1
• InChI key: VHHAZLMVLLIMHT-CUPIEXAXSA-N

Descripción

General description

Chiral Phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides

Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable