555169
Poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)]
light-emitting polymer, predominantly trans
Sinónimos:
Poly(m -phenylenevinylene-co -2,5-dioctoxy-p -phenylenevinylene)
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Quality Level
solubility
chloroform: soluble 2 wt. %
λmax
402 nm
fluorescence
λex 405 nm; λem 452 nm in chloroform
General description
Poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)](PmPV) is a conjugated luminescent polymer with meta linked phenylene ring within the backbone. It has a good non-linear optical response and a high degree of crystallinity.
Semi-conjugated, light-emitting polymer.
Application
PmPV in combination with carbon nanotubes (CNTs), graphene and fullerene forms stable nanocomposites with enhanced electrical and mechanical properties. These composites can potentially be used as semiconducting materials for a variety of electronic applications.
Used in the purification of carbon nanotubes.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Chemically derived, ultrasmooth graphene nanoribbon semiconductors
Li X, et al.
Science, 319(5867), 1229-1232 (2008)
Synthesis and optical properties of phenylene-vinylene copolymers
Davey AP, et al.
Synthetic Metals, 103(1-3), 2478-2479 (1999)
Effective stimulated emission and excited-state absorption cross-section spectra of poly (m-phenylenevinylene-co-2, 5-dioctoxy-p-phenylenevinylene) and t, t?-didecycloxy-II-distyrylbenzene
Holzer W, et al.
Chemical Physics, 224(2-3), 315-326 (1997)
Direct Observation of the Ordering and Molecular Folding of Poly [(m-phenylenevinylene)-co-(2, 5-dioctoxy-p-phenylenevinylene)]
Lei SB, et al.
Advanced Materials, 16(9-10), 828-831 (2004)
A composite from poly (m-phenylenevinylene-co-2, 5-dioctoxy-p-phenylenevinylene) and carbon nanotubes: A novel material for molecular optoelectronics
Curran SA, et al.
Advanced Materials, 10(14), 1091-1093 (1998)
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