459852
9,10-Anthracenedicarbonitrile
97%
Sinónimos:
9,10-Dicyanoanthracene
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About This Item
Fórmula empírica (notación de Hill):
C16H8N2
Número de CAS:
Peso molecular:
228.25
Beilstein/REAXYS Number:
1646384
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
97%
mp
340 °C (lit.)
SMILES string
N#Cc1c2ccccc2c(C#N)c3ccccc13
InChI
1S/C16H8N2/c17-9-15-11-5-1-2-6-12(11)16(10-18)14-8-4-3-7-13(14)15/h1-8H
InChI key
BIOPPFDHKHWJIA-UHFFFAOYSA-N
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Categorías relacionadas
General description
9,10-Anthracenedicarbonitrile (DCA, ADC) is an anthracene derivative. Photochemical reactions of DCA in MeCN-MeOH or MeCN-H2O containing hydroxides or methoxides affords 9-methylimino-10-anthracenecarbonitrile. It participates in the generation of nucleophilic α-hydroxymethyl radicals from α-silyl ethers by irradiation. Binding energy of 9,10-anthracenedicarbonitrile adsorbed onto graphene is -1.23eV.
Application
9,10-Anthracenedicarbonitrile may be used as photosensitizer to investigate the photoisomerization of trans-stilbene (TS) in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H2O system.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Los clientes también vieron
Xia Guo et al.
Journal of colloid and interface science, 283(2), 578-584 (2005-02-22)
Photoisomerization of trans-stilbene (TS) was investigated in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H(2)O systems in order to establish the relationship between the reaction yields and the compositions and structures of molecular organized assemblies. The results show that, in SDS/BA/H(2)O systems
a-Silyl Ethers as Hydroxymethyl Anion Equivalents in Photoinduced Radical Electron Transfer Additions.
Gutenberger G, et al.
Angewandte Chemie (International Edition in English), 37(5), 660-662 (1998)
Steven Bailey et al.
The Journal of chemical physics, 140(5), 054708-054708 (2014-02-12)
To identify families of stable planar anchor groups for use in single molecule electronics, we report detailed results for the binding energies of two families of anthracene and pyrene derivatives adsorbed onto graphene. We find that all the selected derivatives
The photochemical reactions of 9, 10-anthracenedicarbonitrile and 1, 4-naphthalenedicarbonitrile in acetonitrile in the presence of bases.
Freccero M, et al.
Tetrahedron, 50(7), 2115-2130 (1994)
Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids.
Boning W, et al.
The Journal of Physical Chemistry B, 119, 14790-14799 (2015)
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