420727

Chloro(dimethylsulfide)gold(I)

• Sinónimos: (Dimethylsulfide)gold(I) chloride
• Fórmula lineal: (CH₃)₂SAuCl
• Número de CAS: 29892-37-3
• Peso molecular: 294.55
• MDL number: MFCD00192090
• UNSPSC Code: 12161600
• PubChem Substance ID: 24866348
• NACRES: NA.22

Propiedades

• form: powder
• Quality Level: 100
• reaction suitability: core: gold; reagent type: catalyst
• SMILES string: Cl[Au].CSC
• InChI: 1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H/q;+1;/p-1
• InChI key: YQALRAGCVWJXGB-UHFFFAOYSA-M

Descripción

Application

Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:

• chloro(trimesitylphosphine)gold(I)
• gold(I) N-heterocyclic carbene (NHC) complexes
• bis(carbene)gold(I) complex of ferrocenyl complexes
• gold(I) acetylide complexes

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves