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Key Documents

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238732

Sigma-Aldrich

Ammonium trifluoroacetate

98%

Sinónimos:

Trifluoroacetic acid ammonium salt

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About This Item

Fórmula lineal:
CF3CO2NH4
Número de CAS:
3336-58-1
Peso molecular:
131.05
EC Number:
222-072-4
MDL number:
MFCD00012615
UNSPSC Code:
12352302
PubChem Substance ID:
24854342
NACRES:
NA.22

Quality Level

200

assay

98%

form

crystals

mp

123-125 °C (lit.)

SMILES string

N.OC(=O)C(F)(F)F

InChI

1S/C2HF3O2.H3N/c3-2(4,5)1(6)7;/h(H,6,7);1H3

InChI key

YCNIBOIOWCTRCL-UHFFFAOYSA-N

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General description

Ammonium Trifluoroacetate is used as a catalyst in organic synthesis and as an additive in the mobile phase for chiral racemate separation.

Application

Used in the synthesis of hexafluoro-2-aminopentan-4-one ligand and in tuning and calibrating new liquid chromatography/mass spectrometry systems.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Garrett Hellinghausen et al.
Journal of pharmaceutical and biomedical analysis, 155, 70-81 (2018-04-07)
Core-shell particles (superficially porous particles, SPPs) have been proven to provide high-throughput and effective separations of a variety of chiral molecules. However, due to their limited commercialization, many separations have not been reported with these stationary phases. In this study
Ammonium Trifluoroacetate-Mediated Synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones
Chandran R et al.
International Scholarly Research Network, 2011 (2011)
Garrett Hellinghausen et al.
Chirality, 30(9), 1067-1078 (2018-07-04)
A modified macrocyclic glycopeptide-based chiral stationary phase (CSP), prepared via Edman degradation of vancomycin, was evaluated as a chiral selector for the first time. Its applicability was compared with other macrocyclic glycopeptide-based CSPs: TeicoShell and VancoShell. In addition, another modified
Tejas Wattamwar et al.
European journal of mass spectrometry (Chichester, England), 26(2), 117-130 (2019-10-03)
A rapid and sensitive liquid chromatography-mass spectrometry method was developed, optimized, and validated for simultaneous quantification of empagliflozin and metformin in human plasma using empagliflozin D4and metformin D6 as an internal standard. Analytes and internal standard were extracted from plasma
Nimisha Thakur et al.
Chirality, 31(9), 688-699 (2019-07-19)
The enantiomeric excess of chiral starting materials is one of the important factors determining the enantiopurity of products in asymmetric synthesis. Fifty-one commercially available chiral reagents used as building blocks, catalysts, and auxiliaries in various enantioselective syntheses were assayed for
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