20990

Cesium fluoride

purum p.a., ≥98.0%

• Sinónimos: NSC 84270
• Fórmula empírica (notación de Hill): CsF
• Número de CAS: 13400-13-0
• Peso molecular: 151.90
• EC Number: 236-487-3
• MDL number: MFCD00010960
• UNSPSC Code: 12352302
• PubChem Substance ID: 57647889
• NACRES: NA.22

Propiedades

• grade: purum p.a.
• Quality Level: 100
• assay: ≥98.0%
• mp: 682 °C (lit.)
• density: 4.115 g/mL at 25 °C (lit.)
• anion traces: chloride (Cl^-): ≤1000 mg/kg; sulfate (SO₄^2-): ≤500 mg/kg
• cation traces: Ca: ≤50 mg/kg; Cd: ≤50 mg/kg; Co: ≤50 mg/kg; Cu: ≤50 mg/kg; Fe: ≤50 mg/kg; K: ≤300 mg/kg; Na: ≤100 mg/kg; Ni: ≤50 mg/kg; Pb: ≤50 mg/kg; Zn: ≤50 mg/kg
• SMILES string: [F-].[Cs+]
• InChI: 1S/Cs.FH/h;1H/q+1;/p-1
• InChI key: XJHCXCQVJFPJIK-UHFFFAOYSA-M

Descripción

Application

Reactant for:

• Preparation of building blocks for synthesis of fluoroallylic compounds
• Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions
• Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds
• Nucleophilic aromatic substitution (SNAr) reactions

Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa₂O₇, that has applications in photocatalysis and superconductivity.

Other Notes

Catalyst for the reaction of silyl enol ethers with carbonyl compounds

Información de seguridad

• pictograms: GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H302,H318,H361d,H373,H412
• pcodes: P202 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2
• target_organs: Kidney,Adrenal gland
• supp_hazards: EUH032
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 2
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges