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Key Documents

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200050

Sigma-Aldrich

Chromium(III) chloride

purified by sublimation, 99%

Sinónimos:

Chromic chloride, Chromium trichloride

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About This Item

Fórmula lineal:
CrCl3
Número de CAS:
10025-73-7
Peso molecular:
158.36
EC Number:
233-038-3
MDL number:
MFCD00010948
UNSPSC Code:
12352302
PubChem Substance ID:
24851955
NACRES:
NA.23

Quality Level

200

assay

99%

form

flakes

purified by

sublimation

reaction suitability

reagent type: catalyst
core: chromium

impurities

<0.2% water

density

2.87 g/mL at 25 °C (lit.)

SMILES string

Cl[Cr](Cl)Cl

InChI

1S/3ClH.Cr/h3*1H;/q;;;+3/p-3

InChI key

QSWDMMVNRMROPK-UHFFFAOYSA-K

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Application

Chromium(III) chloride can be used in the formation of a catalytic system for the conversion of glucose into 5-hydroxymethylfurfural (HMF). It can also be used in the preparation of ionic liquid mixtures using choline chloride and water with improved ion mobility and conductivity.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.2

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Met. Corr. 1 - Skin Sens. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
MKCW3523
MKCW4391
MKCT0753
MKCR4439
MKCR9790

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Physicochemical properties of ionic liquid mixtures containing choline chloride, chromium (III) chloride and water: effects of temperature and water content
Protsenko VS, et al.
Ionics, 23(3), 637-643 (2017)
J W Boclair et al.
Chemistry of materials : a publication of the American Chemical Society, 11(2), 303-307 (2001-09-07)
Solutions containing divalent metal [M(II) = Mg2+, Zn2+, Co2+, Ni2+, Mn2+] chlorides and CrCl3 6H2O were titrated with NaOH to yield, for M(II) = Zn, Co, and Ni, hydrotalcite-like layered double hydroxides (LDHs), [[M(II)]1-z[Cr(III)]z(OH)2][Cl]z yH2O, in a single step, without
Efficient conversion of glucose into 5-hydroxymethylfurfural by chromium (III) chloride in inexpensive ionic liquid
Hu L, et al.
Industrial & Engineering Chemistry Research, 51(3), 1099-1104 (2012)
M B Hansen et al.
Contact dermatitis, 49(4), 206-212 (2004-03-05)
Most studies investigating chromium allergy have been performed with Cr(VI). However, real exposure to chromium from leather products includes both Cr(III) and Cr(VI). We have determined and compared the minimum elicitation threshold (MET) concentration for Cr(III) and Cr(VI) in Cr(VI)-sensitive
R I Arunkumar et al.
Fish & shellfish immunology, 10(8), 667-676 (2001-02-24)
The objective of this study was to investigate the effect of trivalent (chromic chloride) and hexavalent (potassium dichromate) forms of chromium in the African mouth breeder Oreochromis mossambicus (Peters), with reference to the humoral immune response and lymphoid cells/organs. The
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