184357

(Phenylsulfonyl)acetonitrile

98%

• Fórmula lineal: C₆H₅SO₂CH₂CN
• Número de CAS: 7605-28-9
• Peso molecular: 181.21
• Beilstein/REAXYS Number: 640716
• EC Number: 231-515-0
• MDL number: MFCD00007550
• UNSPSC Code: 12352100
• PubChem Substance ID: 24851110
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: 98%
• form: solid
• mp: 112-114 °C (lit.)
• functional group: nitrile; sulfone
• SMILES string: O=S(=O)(CC#N)c1ccccc1
• InChI: 1S/C8H7NO2S/c9-6-7-12(10,11)8-4-2-1-3-5-8/h1-5H,7H2
• InChI key: ZFCFFNGBCVAUDE-UHFFFAOYSA-N

Descripción

General description

Condensation reaction of (phenylsulfonyl)acetonitrile with benzaldehyde in water in heterogeneous phase in the presence and absence of anionic and cationic surfactants has been studied. Dehydrative alkylation of alcohols with (phenylsulfonyl)acetonitrile under modified Mitsunobu conditions has been investigated.

Application

(Phenylsulfonyl)acetonitrile was used in the synthesis of pyridines, chromenes and thiophene derivatives based on sulfones.

Información de seguridad

• pictograms: GHS06
• signalword: Danger
• hcodes: H301 + H311 + H331
• pcodes: P261 - P264 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Oral
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges