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749141

Sigma-Aldrich

Iron(III) oxo acetate perchlorate hydrate

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Synonym(s):

Hexakis[μ-(acetato-κO:κO′ )]triaqua-μ3-oxotriiron(1+) perchlorate hydrate, Trimeric Fe cluster

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About This Item

Empirical Formula (Hill Notation):
C12H24Fe3O16 · ClO4 · xH2O
Molecular Weight:
691.29 (anhydrous basis)
UNSPSC Code:
26111700
NACRES:
NA.23

form

powder

Quality Level

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General description

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Pictograms

Flame over circle

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Ox. Sol. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Steffen Hausdorf et al.
Journal of the American Chemical Society, 132(32), 10978-10981 (2010-08-12)
A simple two-component procedure was developed to synthesize not only classical zinc-based IRMOFs represented by MOF-5 but also the cobalt and beryllium homologues of this most prominent MOF. The procedure is the first manifestation of mirroring the IRMOF series with
Steffen Hausdorf et al.
Dalton transactions (Cambridge, England : 2003), 7(7), 1107-1113 (2009-03-27)
An ethynylene diisophthalic acid linker molecule was synthesized and used to form a zinc carboxylate-based metal organic framework (MOF) with very large pores and unit cell volume resulting from the unusual combination of structurally different inorganic units forming the secondary
Steffen Hausdorf et al.
The journal of physical chemistry. A, 112(33), 7567-7576 (2008-07-26)
The contributions of terephthalic acid and Zn(2+)-coordinated water in N,N-diethylformamide (DEF) to the overall proton activity in the synthesis of MOF-5 (Zn4O(BDC)3, BDC = 1,4-benzenedicarboxylate) were quantitatively determined by combined electrochemical and UV-vis spectroscopic measurements. Structural transformations of zinc carboxylate-based

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