406139
Chlorodicyclohexylborane
98%
Synonym(s):
Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane
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About This Item
Linear Formula:
(C6H11)2BCl
CAS Number:
Molecular Weight:
212.57
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
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Quality Level
Assay
98%
form
liquid
reaction suitability
reagent type: reductant
bp
100-101 °C/1 mmHg (lit.)
density
0.97 g/mL at 25 °C (lit.)
SMILES string
ClB(C1CCCCC1)C2CCCCC2
InChI
1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChI key
PBBOKJIYEZCTEH-UHFFFAOYSA-N
Related Categories
Application
A convenient reagent for regio- and stereoselective enolboration of ketones and other carbonyl derivatives.
Reactant for:
- Aldol addition reactions
- Mukaiyama aldol addition
- Microwave assisted ring closing metathesis reactions
- C-alkylation of aromatic aldimines
- Reversible ketone-ketone aldol reactions
- Syn- and anti-stereoselective aldol reaction hexenone with aldehydes
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B
Storage Class Code
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
Flash Point(F)
No data available
Flash Point(C)
No data available
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The Journal of Organic Chemistry, 57, 499-499 (1992)
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