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Oxasulfuron

PESTANAL®, analytical standard

Synonym(s):

Oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate

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About This Item

Empirical Formula (Hill Notation):
C17H18N4O6S
CAS Number:
Molecular Weight:
406.41
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

Cc1cc(C)nc(NC(=O)NS(=O)(=O)c2ccccc2C(=O)OC3COC3)n1

InChI

1S/C17H18N4O6S/c1-10-7-11(2)19-16(18-10)20-17(23)21-28(24,25)14-6-4-3-5-13(14)15(22)27-12-8-26-9-12/h3-7,12H,8-9H2,1-2H3,(H2,18,19,20,21,23)

InChI key

IOXAXYHXMLCCJJ-UHFFFAOYSA-N

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General description

Oxasulfuron is a sulfonylurea herbicide, applied on soybean for the post-emergence control of broad-leaf weeds and grasses. Its mode of action involves the inhibition of acetolactate synthase in plants.

Application

Oxasulfuron has been used as an analytical standard to investigate its photochemical degradation in aqueous environment using non-aqueous capillary electrophoresis tandem electrospray mass spectrometry. It may also be used as an analytical reference standard for the quantification of the analyte in environmental samples using high-performance liquid chromatography with diode array detection.
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Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardEnvironment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Novel degradation products of the herbicide oxasulfuron identified by capillary electrophoresis-mass spectrometry
Scrano L, et al.
Environmental Chemistry Letters, 4(4), 225-228 (2006)
The Pesticide Encyclopedia (2014)
Analytical validation method for the determination of sulfonylurea herbicides in water samples by solid-phase extraction and HPLC with diode-array detecton
Proceedings of the 13th International Conference on Environmental ascience and technology, 4(4), 5-7 (2013)
Xinzhou Wu et al.
Journal of agricultural and food chemistry, 66(15), 3966-3974 (2018-03-29)
Matrix-assisted laser desorption/ionization Fourier transform ion cyclotron resonance mass spectrometry (MALDI-FTICR-MS) has been applied for rapid, sensitive, undisputed, and quantitative detection of pesticide residues on fresh leaves with little sample pretreatment. Various pesticides (insecticides, bactericides, herbicides, and acaricides) are detected
Maykel Hernández-Mesa et al.
Journal of chromatography. A, 1617, 460831-460831 (2020-01-18)
This work proposes a novel Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) method in combination with ultra-high performance liquid chromatography-tandem mass spectrometry for the determination of sulfonylurea residues in edible seeds. The chromatographic separation of nine sulfonylureas was accomplished

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