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M51008

Sigma-Aldrich

Methyliminodiacetic acid

99%

Synonym(s):

MIDA, MIDA ligand

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About This Item

Linear Formula:
CH3N(CH2CO2H)2
CAS Number:
4408-64-4
Molecular Weight:
147.13
EC Number:
224-557-6
MDL number:
MFCD00004284
UNSPSC Code:
12352100
PubChem Substance ID:
24896977
NACRES:
NA.22

Assay

99%

mp

220 °C (dec.) (lit.)

SMILES string

CN(CC(O)=O)CC(O)=O

InChI

1S/C5H9NO4/c1-6(2-4(7)8)3-5(9)10/h2-3H2,1H3,(H,7,8)(H,9,10)

InChI key

XWSGEVNYFYKXCP-UHFFFAOYSA-N

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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G B Fiore et al.
Analytical biochemistry, 139(2), 413-417 (1984-06-01)
A method for the separation and quantification of the levels of alanopine and strombine in neutralized, perchloric acid extracts of tissues of marine invertebrates is presented. The method is based on high-performance liquid chromatographic (HPLC) separation, postcolumn derivatization using o-phthaldialdehyde
María Eugenia García-Rubiño et al.
Journal of inorganic biochemistry, 200, 110801-110801 (2019-08-30)
The study of the metal binding pattern of N-methyladenines (1-, 3-, 7- or 9-Meade) towards CuII-iminodiacetate-like chelates is addressed on the basis of XRD crystal structures of sixteen novel ternary compounds. Except for three compounds, all others feature an square-based
M E Haque et al.
Acta medica Okayama, 54(1), 1-8 (2000-03-10)
We present here a reliable and sensitive method for the determination of acidic opines such as meso-alanopine, beta-alanopine, tauropine and strombine in biological samples. Interfering primary amino acids were eliminated by reaction with o-phthalaldehyde, and the derivatized compounds were passed
B Siegmund et al.
Hoppe-Seyler's Zeitschrift fur physiologische Chemie, 364(7), 807-812 (1983-07-01)
meso-Alanopine and D-strombine are separated by high pressure liquid chromatography using a cation exchange resin and 2.5 X 10(-5) M sulfuric acid as eluant, at a flow rate of 1.0 ml/min, 20 degrees C column temperature and a pressure of
Mengping Guo et al.
Organic & biomolecular chemistry, 12(36), 7136-7139 (2014-08-12)
N-Methyliminodiacetic acid (MIDA) as a simple, air stable and water-soluble ligand has been used in the palladium-catalyzed Hiyama cross-coupling reaction of trimethoxyphenylsilane with aryl halides. The yield of the corresponding Hiyama coupling products is high up to around 90% in
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