Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media.

Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media.

Chemical communications (Cambridge, England) (2002-07-19)

Steven V Ley, Chandrashekar Ramarao, Richard S Gordon, Andrew B Holmes, Angus J Morrison, Ian F McConvey, Ian M Shirley, Stephen C Smith, Martin D Smith

PMID12122701

摘要

Palladium(II) acetate microencapsulated in polyurea (MC-[Pd]) is an economical and versatile heterogeneous catalyst for a range of phosphine-free cross-coupling reactions in both conventional solvents and supercritical carbon dioxide (scCO2); the catalyst can be recovered by a simple filtration and recycled up to four times.

材料

货号

品牌

产品描述

520764

Sigma-Aldrich

乙酸钯(II), ≥99.9% trace metals basis

644714

Sigma-Aldrich

Pd EnCat^® 30, extent of labeling: 0.4 mmol/g Pd loading

644722

Sigma-Aldrich

Pd EnCat^® 40, extent of labeling: 0.4 mmol/g Pd loading