Molecular level ordering in poly(2-vinylpyridine).

Molecular level ordering in poly(2-vinylpyridine).

Advanced materials (Deerfield Beach, Fla.) (2012-05-19)

Mohammad Changez, Haeng-Deog Koh, Nam-Goo Kang, Jin-Gyu Kim, Youn-Joong Kim, Shashadhar Samal, Jae-Suk Lee

摘要

The reaction between atactic poly(2-vinylpyridine) and 1,4-dibromobutane leads to formation of long-range 3D molecular ordering in polymer chains mainly because the side group (pyridine) of the polymer chain changes to a syndotactic configuration. This may enable the production of functional molecular devices that operate on a 3D atomic scale.

材料

货号

品牌

产品描述

140805

Sigma-Aldrich

1,4-二溴丁烷, 99%

523321

Supelco

聚(2-乙烯吡啶), analytical standard, average M_w 37,500 (Typical), average M_n 35,000 (Typical)

523356

Supelco

聚(2-乙烯吡啶), analytical standard, average M_w 159,000 (Typical), average M_n 152,000 (Typical)