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Carbopack Carbon Adsorbent

matrix Carbopack Y, 60-80 mesh, bottle of 10 g

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About This Item

EC Number:
UNSPSC Code:
23201100

product name

Carbopack Adsorbent, matrix Carbopack Y, 60-80 mesh, bottle of 10 g

form

granular

packaging

bottle of 10 g

technique(s)

LPLC: suitable

surface area

~24 m2/g

matrix

Carbopack Y

matrix active group

carbon

particle size

60-80 mesh

pore size

~0 cm3/g macroporosity
~0 cm3/g mesoporosity
~0 cm3/g microporosity
~0 Å pore diameter

density

~0.38 g/mL (free fall density)

separation technique

reversed phase

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General description

Carbopack Y was used for determination of contamination caused by pesticides like alachlor, atrazine, captan, formothion, lindane and phosalone in atmospheric samples. Carbopack Y was modified with mono-molecular layer of heptakis-(2,3,6-tri-O-methyl)-ß-cyclodextrin and was used in gas chromatography to study the effect of size and spatial structure of adsorbate molecules on adsorption of organic vapours.
Carbotrap®/Carbopack adsorbent can withstand high bake-out temperature without losing the mechanical and chemical integrity. It has a high affinity for isoprene and does not retain significant amounts of water. Furthermore it has a tendency to pulverize if it is packed too tightly. Carbotrap®/Carbopack adsorbent was used to quantitatively determine trace amounts of volatile organic compounds (VOCs) in air. It was also used for designing sampling protocols on the basis of its retention volume of the gaseous organic compounds of interest.
A graphitized carbon black (GCB) can be non-porous or porous. The graphitization process results in a highly pure surface with great adsorption and desorption (if required) properties. Surface interactions depend solely on dispersion (London) forces. These particles are:
  • Granular
  • Friable
  • Used for molecules with an analyte size relative to C3-C20+ n-alkanes
  • Hydrophobic (can be used in high humidity environments)

Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
  • Particles are 40 mesh and smaller
  • Use 40/60 mesh to prevent channeling (if observed with a 20/40 mesh Carbotrap® adsorbent)
  • Use smaller mesh (60/80, 80/100, etc.) for all other applications
  • Use the smallest particle size available as long as the application can handle the pressure drop

For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon

Legal Information

Carbopack is a trademark of Merck KGaA, Darmstadt, Germany
Carbotrap is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Gas phase retention volume behavior of organic compounds on Carbotrap graphitized carbon.
Pankow JF.
Journal of Chromatography A, 547, 488-493 (1991)
Adsorption of organic vapors on the Carbopack Y carbon adsorbent modified with heptakis-(2, 3, 6-tri-O-methyl)-?-cyclodextrin.
Kudryashov SY, et al.
Russian Journal of Physical Chemistry A, 84 (3), 495-502 (2010)
Comparison of Tenax TA and Carbotrap for sampling and analysis of volatile organic compounds in air.
Rothweiler H, et al.
Atmospheric Environment, 25 (2), 231-235 (1991)
Rybolt et al.
Journal of colloid and interface science, 220(1), 148-156 (1999-11-07)
Second gas-solid virial coefficients were determined at 403.5 +/- 0.5 K for 6 adsorbates, including butane, chloroform, trichlorofluoromethane (Freon 11), bromochloromethane, 1-chloro-2-methylpropane, and dibromodifluoromethane. For another 11 adsorbates, including dichlorodifluoromethane (Freon 12), chlorodifluoromethane (Freon 22), methyl chloride, methylene chloride, propane
Plant Volatile Analysis.
Linskens HF and Jackson JF.
Modern Methods of Plant Analysis, 19, 54-56 (1997)

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