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Sigma-Aldrich

Triethanolamine

puriss. p.a., ≥99% (GC)

Synonym(s):

2,2′,2′′-Nitrilotriethanol, Tris(2-hydroxyethyl)amine

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About This Item

Linear Formula:
(HOCH2CH2)3N
CAS Number:
Molecular Weight:
149.19
Beilstein:
1699263
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

vapor density

5.14 (vs air)

Quality Level

vapor pressure

0.01 mmHg ( 20 °C)

grade

puriss. p.a.

Assay

≥99% (GC)

form

viscous liquid

autoignition temp.

600 °F

expl. lim.

8.5 %

impurities

≤0.0001% heavy metals (as Pb)
≤0.1% ethanolamine
≤0.1% water (Karl Fischer)
≤0.5% diethanolamine (GC)

ign. residue

≤0.005% (as SO4)

refractive index

n20/D 1.485 (lit.)

useful pH range

7.3-8.3

pKa (25 °C)

7.8

bp

190-193 °C/5 mmHg (lit.)

mp

17.9-21 °C (lit.)

transition temp

solidification point 20-22 °C

solubility

soluble 149 g/L at 20 °C (completely)

density

1.124 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤1 mg/kg
sulfate (SO42-): ≤20 mg/kg

cation traces

Fe: ≤1 mg/kg

SMILES string

OCCN(CCO)CCO

InChI

1S/C6H15NO3/c8-4-1-7(2-5-9)3-6-10/h8-10H,1-6H2

InChI key

GSEJCLTVZPLZKY-UHFFFAOYSA-N

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General description

Triethanolamine (TEA) belongs to the family of ethanolamines. It includes the properties of both amines and alcohols.

Application

Triethanolamine may be used as a derivatizing reagent for the determination of boric acid in water samples using gas chromatography-mass spectrometry technique. Addition of triethanolamine to an acidic buffer facilitates the determination of fluoride in inorganic orthophosphates by using a fluoride-selective electrode.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

354.2 °F - closed cup

Flash Point(C)

179 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Fast quantitative analysis of boric acid by gas chromatography-mass spectrometry coupled with a simple and selective derivatization reaction using triethanolamine
Zeng M-L, et al.
Journal of the American Society For Mass Spectrometry, 21(3), 482-485 (2010)
Triethanolamine as an Efficient and Reusable Base, Ligand and Reaction Medium for Phosphane-Free Palladium-Catalyzed Heck Reactions.
Li HJ and Wang L.
European Journal of Organic Chemistry, 22, 5099-5102 (2006)
Toxicology of mono-, di-, and triethanolamine
Knaak BJ, et al.
Reviews of Environmental Contamination and Toxicology, 74(1-86) (1997)
Yuri L Lyubchenko et al.
Methods (San Diego, Calif.), 47(3), 206-213 (2008-10-07)
This paper describes protocols for studies of structure and dynamics of DNA and protein-DNA complexes with atomic force microscopy (AFM) utilizing the surface chemistry approach. The necessary specifics for the preparation of functionalized surfaces and AFM probes with the use
Final report on the safety assessment of triethanolamine, diethanolamine, and monoethanolamine.
Journal of the American College of Toxicology, 2(7), 183-235 (1983)

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