24260

Chlorodicyclohexylborane solution

purum, ~1 M in hexane

• Synonym(s): Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane
• Linear Formula: (C₆H₁₁)₂BCl
• CAS Number: 36140-19-9
• Molecular Weight: 212.57
• Beilstein: 3233942
• MDL number: MFCD00191906
• UNSPSC Code: 12352000
• PubChem Substance ID: 24854571

Properties

• grade: purum
• reaction suitability: reagent type: reductant
• concentration: ~1 M in hexane
• density: 0.74 g/mL at 20 °C
• SMILES string: ClB(C1CCCCC1)C2CCCCC2
• InChI: 1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
• InChI key: PBBOKJIYEZCTEH-UHFFFAOYSA-N

Description

Application

Reactant for:

• Aldol addition reactions
• Mukaiyama aldol addition
• Microwave assisted ring closing metathesis reactions
• C-alkylation of aromatic aldimines
• Reversible ketone-ketone aldol reactions
• Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

Other Notes

Ideal reagent for the generation of E-enol borinates from ketones in high stereoselectivity