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03225

Sigma-Aldrich

1,2,2,6,6-Pentamethyl-4-piperidinol

≥99.0% (GC)

Synonym(s):

4-Hydroxy-1,2,2,6,6-pentamethylpiperidine, HOPEMP, NSC 364075

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About This Item

Empirical Formula (Hill Notation):
C10H21NO
CAS Number:
Molecular Weight:
171.28
Beilstein:
1498
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥99.0% (GC)

impurities

≤1% water

mp

72-76 °C

SMILES string

CN1C(C)(C)CC(O)CC1(C)C

InChI

1S/C10H21NO/c1-9(2)6-8(12)7-10(3,4)11(9)5/h8,12H,6-7H2,1-5H3

InChI key

NWHNXXMYEICZAT-UHFFFAOYSA-N

Application

Reactant for:
Synthesis of photostable blue emitting naphthalimides
Synthesis of blue fluorescent naphthalimide pH chemosensors
Synthesis of crowded piperidines with intramolecularly hydrogen-bonded nitrogen
Synthesis of spiropyrans and spirooxazines
Amine photoredox reactions

Other Notes

Building block for introducing a very hindered-amine

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Corr. 1A - Skin Sens. 1

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

244.4 °F

Flash Point(C)

118 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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S.M. Desai et al.
Macromolecular Symposia, 169, 121-121 (2001)
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J. Macromol. Sci. Chem., A33, 1217-1217 (1996)

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