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95421

Sigma-Aldrich

Bis[tris(4-(heptadecafluorooctyl)phenyl)phosphine]palladium(II) dichloride

≥95.0% (31P-NMR)

Synonym(s):

Bis[tris(4-(perfluorooctyl)phenyl)phosphine]palladium(II) dichloride

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About This Item

Empirical Formula (Hill Notation):
C84H24Cl2F102P2Pd
CAS Number:
326475-44-9
Molecular Weight:
3210.20
MDL number:
MFCD04040059
UNSPSC Code:
12352200

Assay

≥95.0% (31P-NMR)

Application

Catalyst for Stille and Suzuki couplings in "Fluorous Biphase Systems" (FBS)

Other Notes

Perfluoro-tagged Pd complexes as catalysts for Stille couplings in a fluorous biphase system, palladium-catalyzed Suzuki couplings.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1

Target Organs

Liver

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
63975/1
063975/1

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T. Osswald et al.
Tetrahedron Letters, 42, 2965-2965 (2001)
S. Schneider et al.
Helvetica Chimica Acta, 84, 735-735 (2001)
S. Schneider et al.
Angewandte Chemie (International Edition in English), 112, 4293-4293 (2000)

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