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902985

Sigma-Aldrich

(Bathocuproine)NiBr2

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About This Item

Empirical Formula (Hill Notation):
C26H20Br2N2Ni
CAS Number:
326822-02-0
Molecular Weight:
578.95
UNSPSC Code:
12161600
NACRES:
NA.22

form

powder or crystals

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

>300 °C

SMILES string

CC1=NC2=C(C=CC(C(C3=CC=CC=C3)=C4)=C2N=C4C)C(C5=CC=CC=C5)=C1.Br[Ni](C)(C)Br

Related Categories

Application

Catalyst for C-alkylation of nitroalkanes with unactivated alkyl iodides

Other Notes

Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Sina Rezazadeh et al.
Journal of the American Chemical Society, 139(24), 8110-8113 (2017-06-09)
Enabled by nickel catalysis, a mild and general catalytic method for C-alkylation of nitroalkanes with unactivated alkyl iodides is described. Compatible with primary, secondary, and tertiary alkyl iodides; and tolerant of a wide range of functional groups, this method allows

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Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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