670650
(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine
97%
Synonym(s):
(1R)-trans-N-Boc-1,2-diaminocyclohexane
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About This Item
Empirical Formula (Hill Notation):
C11H22N2O2
CAS Number:
Molecular Weight:
214.30
Beilstein:
7023564
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
≥96.5%
97%
form
solid
optical activity
[α]/D -26±2°, c = 1 in chloroform
optical purity
ee: ≥99.0%
functional group
amine
SMILES string
CC(C)(C)OC(=O)N[C@@H]1CCCC[C@H]1N
InChI
1S/C11H22N2O2/c1-11(2,3)15-10(14)13-9-7-5-4-6-8(9)12/h8-9H,4-7,12H2,1-3H3,(H,13,14)/t8-,9-/m1/s1
InChI key
AKVIZYGPJIWKOS-RKDXNWHRSA-N
Application
(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:
- An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
- A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Find documentation for the products that you have recently purchased in the Document Library.
Robust and Recyclable Self-Supported Chiral Nickel Catalyst for the Enantioselective Michael Addition
Bissessar D, et al.
advanced synthesis and catalysis, 358(12), 1982-1988 (2016)
Enantioselective Desymmetrization of Prochiral Cyclohexanones by Organocatalytic Intramolecular Michael Additions to α,β-Unsaturated Esters
Gammack Y, et al.
Angewandte Chemie (International Edition in English), 54(16), 4899-4903 (2015)
Robust and Recyclable Self-Supported Chiral Nickel Catalyst for the Enantioselective Michael Addition
Bissessar D, et al.
Advanced Synthesis & Catalysis, 358(12), 1982-1988 (2016)
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