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592552

Sigma-Aldrich

Pentabromophenyl acrylate

96%

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About This Item

Linear Formula:
Br5C6OCOCH=CH2
CAS Number:
52660-82-9
Molecular Weight:
542.64
MDL number:
MFCD00080604
UNSPSC Code:
12352103
PubChem Substance ID:
24881397
NACRES:
NA.23

Assay

96%

form

solid

mp

148-151 °C (lit.)

storage temp.

−20°C

SMILES string

Brc1c(Br)c(Br)c(OC(=O)C=C)c(Br)c1Br

InChI

1S/C9H3Br5O2/c1-2-3(15)16-9-7(13)5(11)4(10)6(12)8(9)14/h2H,1H2

InChI key

BKKVYNMMVYEBGR-UHFFFAOYSA-N

Application

Pentabromophenyl acrylate can form copolymers with acrylonitrile in aqueous emulsions or in the presence of a free radical initiator.

Other Notes

Monomer used to make high refractive index polymer for optical waveguides.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Copolymers of acrylonitrile with some brominated acrylates.
Janovic Z, et al.
J. Macromol. Sci. Chem., 19(8-9), 1137-1152 (1983)
Olesya Daikos et al.
Physical chemistry chemical physics : PCCP, 18(47), 32369-32377 (2016-11-18)
Pentabrominated and fluorinated aromatic (meth)acrylates as well as their non-halogenated counterparts have been studied with the aim to avoid conventional photoinitiators and to overcome some negative consequences related to their use. Therefore, RTIR spectroscopy, laser flash photolysis and GC/MS were

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Materials for High and Low Refractive Index Coatings

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