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540390

Sigma-Aldrich

(3,4-Dihydro-1-naphthyloxy)trimethylsilane

97%

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About This Item

Empirical Formula (Hill Notation):
C13H18OSi
CAS Number:
38858-72-9
Molecular Weight:
218.37
MDL number:
MFCD03093969
UNSPSC Code:
12352100
PubChem Substance ID:
24878464
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.5287 (lit.)

bp

63-65 °C/0.01 mmHg (lit.)

density

0.983 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)OC1=CCCc2ccccc12

InChI

1S/C13H18OSi/c1-15(2,3)14-13-10-6-8-11-7-4-5-9-12(11)13/h4-5,7,9-10H,6,8H2,1-3H3

InChI key

CAUIWDWUUCGKBV-UHFFFAOYSA-N

General description

(3,4-Dihydro-1-naphthyloxy)trimethylsilane (3,4-dihydronaphthalen-1-yloxy(trimethyl)silane) is a protected phenol. Its IR spectral analysis suggests νmax (DCM) = 1638cm-1.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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William J Kerr et al.
Chemical communications (Cambridge, England), (47)(47), 5049-5051 (2007-12-01)
Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures.

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