369330

N-tert-Butyltrimethylsilylamine

98%

• Synonym(s): N-(Trimethylsilyl)-tert-butylamine
• Linear Formula: (CH₃)₃SiNHC(CH₃)₃
• CAS Number: 5577-67-3
• Molecular Weight: 145.32
• Beilstein: 1734528
• MDL number: MFCD00054891
• UNSPSC Code: 12352100
• PubChem Substance ID: 24862959
• NACRES: NA.22

Properties

• Assay: 98%
• form: liquid
• refractive index: n20/D 1.406 (lit.)
• bp: 118-119 °C (lit.)
• density: 0.762 g/mL at 25 °C (lit.)
• SMILES string: CC(C)(C)N[Si](C)(C)C
• InChI: 1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
• InChI key: GVHIREZHTRULPT-UHFFFAOYSA-N

Description

General description

N-tert-Butyltrimethylsilylamine (Me₃SiNH-t-Bu) reacts with [Cp*Rh(H₂O)₃](OTf)₂ in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh₃(μ-OH)3(μ₃-OH)](OTf)₃(t-BuNH₃).

Application

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Safety Information

• Pictograms: GHS02,GHS05
• Signal Word: Danger
• Hazard Statements: H226,H314
• Precautionary Statements: P280 - P305 + P351 + P338 - P310
• Hazard Classifications: Flam. Liq. 3 - Skin Corr. 1B
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 78.8 °F - closed cup
• Flash Point(C): 26 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves