182702
Poly(vinylidene fluoride)
average Mw ~534,000 by GPC, powder
Synonym(s):
PVDF
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About This Item
Linear Formula:
(CH2CF2)n
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
vapor pressure
15 mmHg ( 32 °C)
form
powder
mol wt
average Mw ~534,000 by GPC
refractive index
n20/D 1.42
transition temp
Tg −38 °C
Tm 171 °C
density
1.74 g/mL at 25 °C
SMILES string
FC(F)=C
InChI
1S/C2H2F2/c1-2(3)4/h1H2
InChI key
BQCIDUSAKPWEOX-UHFFFAOYSA-N
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General description
Poly(vinylidene fluoride) PVDF is a semi crystalline non-centrosymmetric polymer which exhibits piezo-, pyro- and ferroelectric properties. It is a linear polymer that shows permanent electric dipoles perpendicular to the direction of the molecular chain. These dipoles result from the difference in electronegativity between the atoms of hydrogen and fluorine with respect to carbon. Depending on the processing conditions, PVDF exhibits several different crystalline phases (α,β,γ,δ). The β phase of PVDF is the phase that exhibits the best ferroelectric and piezoelectric properties.
Application
Poly(vinylidene fluoride) (PVDF) is used in nanoporous electrodes. It is used to synthesize composites comprising of ultrafine fibers of PVDF embedded with carbon nanotubes. It can be used in sensors, actuators, for energy storage, sphygmomanometers, pressure sensors and nanogenerators, lithium ion batteries. Additionally, it may find application as matrix for PVDF-nanoclay nanocomposites and PVDF acrylic rubber/clay nanocomposite hybrid.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Hot Plate Annealing at a Low Temperature of a Thin Ferroelectric P(VDF-TrFE) Film with an Improved Crystalline Structure for Sensors and Actuators.
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Wenzhong Ma et al.
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The crystallization behaviors of two copolymers of PVDF were studied, and the effect of copolymerized chains on the crystallization behavior was investigated. The results indicated that both copolymers had a lowered crystallization temperature and crystallinity. The crystallization rate was improved
Chi Yan Lai et al.
Membranes, 4(1), 55-78 (2014-06-25)
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Shu-Hua Wang et al.
Nanoscale research letters, 9(1), 522-522 (2014-10-08)
Poly(vinylidene fluoride) (PVDF) ultrafine fibers with different proportions of multi-walled carbon nanotube (MWCNT) embedded have been fabricated using a modified electrospinning device with a rotating collector. With the increasing of MWCNT content, the β phase was noticeable enhanced, and the
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