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215996

Sigma-Aldrich

Ammonium phosphate dibasic

ACS reagent, ≥98%

Synonym(s):

Ammonium hydrogenphosphate, Diammonium hydrogenphosphate, di-Ammonium hydrogenphosphate (sec)

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About This Item

Linear Formula:
(NH4)2HPO4
CAS Number:
7783-28-0
Molecular Weight:
132.06
EC Number:
231-987-8
MDL number:
MFCD00010891
UNSPSC Code:
12352300
PubChem Substance ID:
329752180
NACRES:
NA.21
Assay:
≥98%
grade:
ACS reagent
form:
crystals or chunks
powder
Pricing and availability is not currently available.

grade

ACS reagent

Quality Level

200

Assay

≥98%

form

crystals or chunks
powder

impurities

≤0.005% NH4OH pptd.
≤0.005% insolubles

pH

7.7-8.1 (25 °C, 5%)

mp

155 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤0.001%
nitrate (NO3-): ≤0.003%
sulfate (SO42-): ≤0.01%

cation traces

Ca: 0.001%
Fe: ≤0.001%
K: ≤0.005%
Mg: 0.0005%
Na: ≤0.005%
heavy metals (as Pb): ≤0.001%

SMILES string

N.N.OP(O)(O)=O

InChI

1S/2H3N.H3O4P/c;;1-5(2,3)4/h2*1H3;(H3,1,2,3,4)

InChI key

MNNHAPBLZZVQHP-UHFFFAOYSA-N

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General description

Ammonium phosphate dibasic is a water-soluble ammonium phosphate salt. It is a key component of phosphate fertilizers. It is commonly used as a flame retardant for plywood, paper, and fabrics, as well as a corrosion inhibitor consolidant for degraded carbonatic materials found in old buildings. [1]

Application

Ammonium phosphate dibasic can be used as a catalyst:
  • To synthesize tetrahydrobenzo[b]pyranderivatives via three‐component condensation reaction.
  • In the solvent-free Biginelli reactions.
  • To synthesize bis(indolyl)methanes via solvent-free reaction of indole derivatives and aromatic or aliphatic aldehydes.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV9635
MKCX0690
MKCV9636
MKCX0689
MKCW3063

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Matteo Frasnelli et al.
Acta biomaterialia, 33, 283-289 (2016-01-23)
The beta to alpha transition in tricalcium phosphate (TCP) bioceramics containing different amount of magnesium was studied in the present work. Mg-doped TCP powder was obtained by solid-state reaction starting from pure calcium carbonate, ammonium phosphate dibasic and magnesium oxide
Ash M and Ash I.
Handbook of Green Chemicals, 627-627 (2004)
Diammonium hydrogenphosphate for the consolidation of building materials. Investigation of newly-formed calcium phosphates.
Elena P, et al.
Construction Building Materials, 195, 557-563 (2019)
Hydrothermal synthesis, structures and luminescent properties of nanocrystaline Ca8Gd2(PO4)6O2: Eu2+, Eu3+ phosphors.
Bharat L, et al.
Chemical Engineering Journal, 240, 179-186 (2014)
Study of metastable equilibria in the ternary system NH4H 2PO4-(NH4)2HPO4-H2O at -7 and -9 ?C.
Zerrouk L, et al.
Fluid Phase Equilibria, 354, 47-53 (2013)
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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