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243450

Sigma-Aldrich

Tellurium dioxide

≥99%

Synonym(s):

Tellurium(IV) oxide

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About This Item

Linear Formula:
TeO2
CAS Number:
Molecular Weight:
159.60
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.23
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Quality Level

Assay

≥99%

form

powder

mp

733 °C (lit.)

density

5.67 g/mL at 25 °C (lit.)

SMILES string

O=[Te]=O

InChI

1S/O2Te/c1-3-2

InChI key

LAJZODKXOMJMPK-UHFFFAOYSA-N

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General description

Tellurium dioxide, also known as tellurium(IV) oxide, is a white, crystalline solid with a melting point of 1,130 °C and a boiling point of 1,850 °C. Tellurium dioxide is an important material in a number of applications, including as a catalyst in the synthesis of plastics resins, and pharmaceuticals, and as a component in tellurium-based alloys. Tellurium dioxide is typically made at high temperatures either by decomposition of tellurium(IV) chloride or tellurium(IV) sulfate in the presence of oxygen.

Application

Tellurium dioxide is used to prepare tellurium metal, telluric acid, and many tellurium salts.[1] It may also be used in the preparation of Ag2Te nanoparticles.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Lact. - Repr. 1B - Skin Sens. 1B

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Mao Shen et al.
Nanoscale research letters, 8(1), 253-253 (2013-05-31)
A facile one-step synthesis of CdTe quantum dots (QDs) in aqueous solution by atmospheric microwave reactor has been developed using 3-mercaptopropionic acid reduction of TeO2 directly. The obtained CdTe QDs were characterized by ultraviolet-visible spectroscopy, fluorescent spectroscopy, X-ray powder diffraction
Tingjun Wu et al.
Frontiers in chemistry, 8, 84-84 (2020-03-21)
A systematic electrochemical study was conducted to investigate the reduction of tellurium (Te) in alkaline solutions. The effect of various parameters, including tellurite ion concentration, applied potential, and pH was investigated by both linear sweep voltammograms (LSVs) and electrochemical quartz
G Bilir et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 314-321 (2011-09-20)
TeO(2)-CdF(2)-WO(3) glasses with various compositions and Er(3+) concentrations were prepared by conventional melting method. Their optical properties were studied by measuring the absorption, luminescence spectra and the decay patterns at room temperature. From the optical absorption spectra the Judd-Ofelt parameters
Sankha Chattopadhyay et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 68(10), 1967-1969 (2010-05-18)
A simple and inexpensive ion-exchange chromatography method for the separation of medically useful no-carrier-added (nca) iodine radionuclides from bulk amounts of irradiated tellurium dioxide (TeO(2)) target was developed and tested using (131)I. The radiochemical separation was performed using a very
Edmond P F Lee et al.
The Journal of chemical physics, 121(7), 2962-2974 (2004-08-05)
Ab initio calculations have been carried out on low-lying singlet and triplet states of TeO2 at different levels of theory with basis sets of up to the augmented-polarized valence-quintuple-zeta quality. Equilibrium geometrical parameters, harmonic vibrational frequencies, and relative electronic energies

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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