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Merck

CRM72839

Supelco

O-Ethyl O-(4-nitrophenyl) phenylphosphonothioate

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Sinónimos:

O-Ethyl O-(4-nitrophenyl) phenylphosphonothioate

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About This Item

Fórmula empírica (notación de Hill):
C14H14NO4PS
Número de CAS:
Peso molecular:
323.30
Beilstein/REAXYS Number:
2542580
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

format

neat

storage temp.

2-8°C

SMILES string

CCOP(=S)(Oc1ccc(cc1)[N+]([O-])=O)c2ccccc2

InChI

1S/C14H14NO4PS/c1-2-18-20(21,14-6-4-3-5-7-14)19-13-10-8-12(9-11-13)15(16)17/h3-11H,2H2,1H3

InChI key

AIGRXSNSLVJMEA-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

EPN is a non-systemic organophosphate insecticide that inhibits the activity of acetylcholinesterase (AChE) and causes hyper excitation. Activated by contact and ingestion, it is used for protection against lepidopteran and other leaf-eating larvae.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, EPN is not approved for use in the European Union as a plant protection agent.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
EPN CRM may find the following uses:

  • Development of a method to analyze 142 insecticide residues in weed and agricultural crops samples by dispersive solid-phase extraction (d-SPE) extraction and liquid chromatographic-mass spectrometric determination (LC-MS)
  • Simultaneous analysis of eight pesticide residues in green tea leaves and infusion samples by gas chromatography (GC) micro electron capture detector (μECD), followed by a confirmation using GC/tandem mass spectrometry (GC/MS/MS)
  • Employing thin-layer chromatography/direct analysis in real-time time-of-flight mass spectrometry (TLC/DART-TOFMS) along with isotope dilution technique for the determination of organophosphorus insecticides in dumpling and grapefruit samples
  • Multi-analysis of 131 pesticide residues in different types of tea samples by dispersive solid-phase extraction (d-SPE) and gel permeation chromatography-gas chromatography-tandem mass spectrometry (GPC-GC-MS/MS)
  • Qualitative and quantitative analysis of 412 pesticide residues from different chemical classes in cotton samples using GC-MS/MS and LC-MS/MS
  • Investigate the presence of 160 pesticide residues simultaneously in chamomile, thyme, and marjoram samples by GC-MS/MS

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Certificados de análisis (COA)

Lot/Batch Number

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Visite la Librería de documentos

Development and validation of multi-residue method for determination of 412 pesticide residues in cotton fiber using GC-MS/MS and LC-MS/MS
Attallah ER, et al.
The Journal of The Textile Institute, 109(1), 46-63 (2018)
Osamu Kiguchi et al.
Journal of chromatography. A, 1370, 246-254 (2014-12-03)
To assess food safety emergencies caused by highly hazardous chemical-tainted foods, simultaneous analysis of organophosphorus insecticides in fatty foods such as precooked foods was conducted using thin-layer chromatography/direct analysis in real time time-of-flight mass spectrometry (TLC/DART-TOFMS) and isotope dilution technique.

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