CRM44794

Phosphamidon

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Sinónimos: 2-Chloro-N,N-diethyl-3-(dimethylphosphono)crotonic amide
• Fórmula empírica (notación de Hill): C₁₀H₁₉ClNO₅P
• Número de CAS: 13171-21-6
• Peso molecular: 299.69
• Beilstein: 8323501
• Número MDL: MFCD00055301
• Código UNSPSC: 41116107
• NACRES: NA.24

Propiedades

• grado: certified reference material; TraceCERT^®
• Nivel de calidad: 300
• Línea del producto: TraceCERT^®
• caducidad: limited shelf life, expiry date on the label
• fabricante / nombre comercial: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• Formato: neat
• temp. de almacenamiento: −20°C
• cadena SMILES: CCN(CC)C(=O)\C(Cl)=C(\C)OP(=O)(OC)OC
• InChI: 1S/C10H19ClNO5P/c1-6-12(7-2)10(13)9(11)8(3)17-18(14,15-4)16-5/h6-7H2,1-5H3/b9-8+
• Clave InChI: RGCLLPNLLBQHPF-CMDGGOBGSA-N

Descripción

Descripción general

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.

Aplicación

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The phosphamidon CRM may also find following uses:

• Determination of five organophosphorus pesticides in a medicinal herb sample using QuEChERS along with dispersive liquid-liquid microextraction (DLLME) and stacking followed by micellar electrokinetic chromatography (MEKC)
• Magnetic solid phase microextraction (MSPE) of five organophosphorus pesticides using graphene based cyanopropyltriethoxysilane as an adsorbent from cow′s milk samples and their subsequent determination by gas chromatography with micro-electron capture detector
• Investigation of residue levels of highly toxic pesticides in 6554 samples of fruits and vegetables by quadrupole time-of-flight LC/MS
• Analysis of 4 organophosphorus pesticides by gas chromatography with microelectron capture detector following their extraction using a newly synthesized magnetic hybrid material as a solid phase extraction adsorbent
• Multi-residue analysis of 44 organophosphorus pesticides by QuEChERS method combined with gas chromatography in Pogostemon cablin samples
• Detection of organophosphorus pesticides in Chinese cabbage sample by a newly designed positive photoionization-ion mobility spectrometry (PP-IMS) apparatus

Información legal

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Información de seguridad

• Pictogramas: GHS06,GHS08,GHS09
• Palabra de señalización: Danger
• Frases de peligro: H300,H311,H341,H410
• Consejos de prudencia: P202 - P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312
• Clasificaciones de peligro: Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2
• Código de clase de almacenamiento: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable