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Merck

258105

Sigma-Aldrich

Ácido sulfúrico

Sulfuric acid
1 of 2 reviewers received a sample product or took part in a promotion

ACS reagent, 95.0-98.0%

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About This Item

Fórmula lineal:
H2SO4
Número de CAS:
Peso molecular:
98.08
Beilstein:
2037554
Número CE:
Número MDL:
Código UNSPSC:
12352106
ID de la sustancia en PubChem:
NACRES:
NA.21
En este momento no podemos mostrarle ni los precios ni la disponibilidad

grado

ACS reagent

Nivel de calidad

Agency

suitable for EPA 1613
suitable for SM 4500 - NH3
suitable for SM 5210

densidad de vapor

<0.3 (25 °C, vs air)

presión de vapor

1 mmHg ( 146 °C)

descripción

Free from suspended or insoluble matter
Nominally 95-98% H2SO4

Ensayo

95.0-98.0%

Formulario

liquid

residuo de ign.

≤5 ppm

color

APHA: ≤10

pH

1.2 (5 g/L)

bp

~290 °C (lit.)

densidad

1.840 g/mL at 25 °C (lit.)

trazas de anión

MnO4- reducers: ≤2 ppm
chloride (Cl-): ≤0.2 ppm
nitrate (NO3-): ≤0.5 ppm

trazas de catión

As: ≤0.01 ppm
Fe: ≤0.2 ppm
Hg: ≤5 ppb
NH4+: ≤2 ppm
heavy metals: ≤1 ppm (by ICP)

aplicaciones

PFAS testing

cadena SMILES

OS(O)(=O)=O

InChI

1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)

Clave InChI

QAOWNCQODCNURD-UHFFFAOYSA-N

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Aplicación

El ácido sulfúrico puede utilizarse como catalizador:
  • En la hidrólisis de sales de nitroalcanos primarios o secundarios a aldehídos o cetonas.
  • En la hidrólisis selectiva de nitrilos a amidas.
  • Para sintetizar amidas de t-alquilcarbinaminas mediante la reacción de Ritter entre nitrilos y alquenos.
  • Para preparar 3,4-dialquil-2(5H)-furanonas por carbonilación de aldehídos α,β-insaturados.
  • En la nitración de carbociclos aromáticos y compuestos heteroaromáticos.
  • En la síntesis de cetonas de Friedel-Craft usando anhídridos mediante la reacción de α-amidoalquilación.

El H2SO4 se puede utilizar también en las siguientes reacciones:
  • Reacciones de adición de Michael
  • Reacciones de sustitución electrófila
  • Esterificación de ácidos aromáticos muy ocultos
  • Reacción de condensación aldólica
  • Transposición de Beckmann
  • Reacción de Hofmann-Loffler-Freytag
  • Isomerización
  • Deshidrogenación
  • Sulfonación

Otras notas

Mismas especificaciones ACS que el producto 320501
4 l y 4 X 4l se envasan en botellas de polietileno
Número de referencia (SKU)-tamaños de envase con -PC vienen envasados en botellas de vidrio recubiertas de PVC.

Pictogramas

Corrosion

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Código de clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Certificados de análisis (COA)

Lot/Batch Number

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Questions

1–9 of 9 Questions  
  1. Is the range of concentration listed have to do with volume or will an exact percentage be available on the bottle when received for the purposes of further dilution.

    1 answer
    1. The specification for this product (95.0 to 98.0 percent) is for the weight percent of the sulfuric acid; the remaining 2 to 5 percent by weight is water. The lot-specific weight percent is reported as the Purity by Sodium Hydroxide (NaOH) titration on the certificate of analysis for each lot. The result is not printed on the bottle. Practically speaking, whether the percentage is 95.0 percent or 98.0 percent or somewhere in between, the material would be handled the same way.

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. Difference between 258105-500ML, and 258105-500ML-PC, Mainly the PC part of the partnumber.

    1 answer
    1. Product 258105-500ML is packaged in a poly bottle, The package sizes listing the -PC suffix, including 258105-500ML-PC, are packaged in PVC-coated glass bottles.

      Helpful?

  5. How was the concentration of Sulfuric acid, Product 258105, calculated?

    1 answer
    1. The molarity is calculated using the following equation:molarity=[(1000 X Density)/molecular weight] X (percent purity/100).

      Helpful?

  6. What is the concentration of Sulfuric acid, Product 258105, in moles per liter (M)?

    1 answer
    1. This material has a calculated, theoretical concentration of 18 M.

      Helpful?

  7. How is Sulfuric acid, Product 258105, to be stored?

    1 answer
    1. This material is a room temperature storage item.

      Helpful?

  8. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  9. What is Sulfuric acid, Product 258105, dissolved in?

    1 answer
    1. This material is not dissolved in anything.  Rather it is pure sulfuric acid, which is a liquid at room temperature.

      Helpful?

Reviews

1 of 2 reviewers received a sample product or took part in a promotion

Active Filters

  1. 2 Ratings-Only Reviews

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