937118

QPhos Pd G3 ChemBeads

• Sinónimos: QPhos G3 Palladacycle ChemBeads, QPhos Palladacycle ChemBeads, [2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][1′-[bis(1,1-dimethylethyl)phosphino]-1,2,3,4,5-pentaphenylferrocene](methanesulfonato-κO)palladium ChemBeads
• Fórmula empírica (notación de Hill): C₆₁H₆₀FeNO₃PPdS
• Número de CAS: 2021255-91-2
• Peso molecular: 1080.44
• UNSPSC Code: 12352100

Propiedades

• form: solid
• Quality Level: 100
• composition: , 4-6 wt. % (loading)
• reaction suitability: reagent type: catalyst
• SMILES string: O=S(=O)([O-][Pd+2]1([C-]=2C=CC=CC2C=3C=CC=CC3[NH2]1)[P](C(C)(C)C)(C(C)(C)C)[C-]45[CH]6=[CH]7[CH]8=[CH]4[Fe+2]7869%10%11%125C=%13(C=%14C=CC=CC%14)C%12(C=%15C=CC=CC%15)=C%11(C=%16C=CC=CC%16)[C-]%10(C=%17C=CC=CC%17)C%139C=%18C=CC=CC%18)C
• InChI: InChI=1S/C35H25.C13H22P.C12H10N.CH4O3S.Fe.Pd/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h1-25H;7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q3*-1;;2*+2/p-1
• InChI key: NNVAEYGNFLUPRU-UHFFFAOYSA-M

Descripción

General description

The ChemBeads product of the QPhos ligand combined with the Buchwald third Generation Palladacycle. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE). QPhos Pd G3 has been used in:

• The synthesis of complex druglike moleucle via Negisihi couplings using a high-throughput experimentation approach.[1]
• The regioselective arylboration of isoprene using cooperative Pd/Cu catalysis.[2]
• The total synthesis of Phainanoid A and its synthetic analogues.[3][4]

Application

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For general uses, product is also available in powdered form 903027

Features and Benefits

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3