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Merck

B32807

Sigma-Aldrich

Benzyltriphenylphosphonium chloride

99%

Sinónimos:

BTPPC, NSC 116712, Triphenyl(phenylmethyl)phosphonium chloride

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About This Item

Fórmula lineal:
C6H5CH2P(Cl)(C6H5)3
Número de CAS:
Peso molecular:
388.87
Beilstein:
3599868
Número CE:
Número MDL:
Código UNSPSC:
12352107
ID de la sustancia en PubChem:
NACRES:
NA.22
En este momento no podemos mostrarle ni los precios ni la disponibilidad

Nivel de calidad

Ensayo

99%

Formulario

powder

idoneidad de la reacción

reaction type: C-C Bond Formation

mp

≥300 °C (lit.)

cadena SMILES

[Cl-].C(c1ccccc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C25H22P.ClH/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1

Clave InChI

USFRYJRPHFMVBZ-UHFFFAOYSA-M

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Aplicación

Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
  • Platinum chloro-tetrazole complexes via azidation.[1]
  • Trans-stilbenes and cinnamates via Wittig olefination.[2]
  • Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.[3]
  • Pentiptycenes for use as light-driven molecular brakes.[4]
  • Archipelago structures for formation of petroleum asphaltenes.[5]


It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.[6]
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites

Reactant for synthesis of:
  • Platinum chloro tetrazole complexes via azidation
  • Trans-stilbenes and cinnamates via Wittig olefination
  • Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
  • Pentiptycenes for use as light-driven molecular brakes

Reactant for formation of archipelago structures for formation of petroleum asphaltenes

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT RE 1 - STOT SE 3

Órganos de actuación

Lungs,nasal cavity, Respiratory system

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

572.0 °F - closed cup

Punto de inflamabilidad (°C)

300 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Certificados de análisis (COA)

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Visite la Librería de documentos

Pentiptycene?Derived Light?Driven Molecular Brakes: Substituent Effects of the Brake Component.
Sun W T, et al.
Chemistry?A European Journal , 16(38), 11594-11604 (2010)
Orally active achiral N-hydroxyformamide inhibitors of ADAM-TS4 (aggrecanase-1) and ADAM-TS5 (aggrecanase-2) for the treatment of osteoarthritis.
De Savi , et al.
Bioorganic & Medicinal Chemistry Letters, 21(11), 3301-3306 (2011)
Synthesis and tyrosinase inhibition activity of trans-stilbene derivatives.
Ismail T, et al.
Bioorganic Chemistry, 64, 97-102 (2016)
A new route to N (1)-5R-tetrazole complexes via azidation to nitriles coordinated to Pt (II) and Pt (IV).
Popova E A, et al.
Inorgorganica Chimica Acta, 375(1), 242-247 (2011)
Tube-like natural halloysite/fluoroelastomer nanocomposites with simultaneous enhanced mechanical, dynamic mechanical and thermal properties.
Rooj S, et al.
European Polymer Journal, 47(9), 1746-1755 (2011)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the shelf life for this product?

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

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