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Merck

86578

Sigma-Aldrich

Ortosilicato de tetraetilo

≥99.0% (GC)

Sinónimos:

Silicato de tetraetilo, TEOS, Tetraetoxisilano, Tetraetoxisilicio(IV), Tetraetóxido de silicio, Éster tetraetílico del ácido ortosilícico

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About This Item

Fórmula lineal:
Si(OC2H5)4
Número de CAS:
Peso molecular:
208.33
Beilstein:
1422225
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.22
Ensayo:
≥99.0% (GC)
bp:
168 °C (lit.)
presión de vapor:
<1 mmHg ( 20 °C)
En este momento no podemos mostrarle ni los precios ni la disponibilidad

densidad de vapor

7.2 (vs air)

Nivel de calidad

presión de vapor

<1 mmHg ( 20 °C)

Ensayo

≥99.0% (GC)

Formulario

liquid

índice de refracción

n20/D 1.382 (lit.)
n20/D 1.383

bp

168 °C (lit.)

densidad

0.933 g/mL at 20 °C (lit.)

cadena SMILES

CCO[Si](OCC)(OCC)OCC

InChI

1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3

Clave InChI

BOTDANWDWHJENH-UHFFFAOYSA-N

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Descripción general

El ortosilicato de tetraetilo (TEOS) es un material inorgánico que puede usarse como fuente de sílice para la síntesis de materiales a base de sílice como el dióxido de silicio,[1] los oxicarburos de silicio,[2] el silanol,[3] el polímero de siloxano[4] y películas delgadas de organosilicio[5] para una variedad de aplicaciones. Puede utilizarse también en la síntesis de membranas mezcladas y en la producción de aerogeles.[6] Otras aplicaciones son los revestimientos para alfombras y otros objetos.[7]

Aplicación

El ortosilicato de tetraetilo (TEOS) puede utilizarse:
  • Como reactivo junto con el cloruro férrico en la síntesis de dihidropirimidinonas.[8]
  • Como modificador en la fabricación del sensor de humedad, poli(2-acrilamido-2-metilpropano sulfonato) (poli-AMPS).[9]
  • Como medio para sintetizar triarilaminas y éteres diarílicos a través de la reacción de Ullmann sin ligando, catalizada por cobre.[10]
  • Como precursor para la preparación de xerogel de sílice que encuentra aplicación en los portadores de fármacos.[11]
  • Como precursor para la síntesis de partículas esféricas de sílice por el proceso Stober.[12]

Interaccionará con la dodecilamina en la formación de compuestos de intercalación de H+-magadiita y se utilizó en un estudio de vidrios bioactivos de metales mixtos.
Utilizado normalmente como precursor para preparar xerogeles

Pictogramas

FlameExclamation mark

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

113.0 °F - closed cup

Punto de inflamabilidad (°C)

45 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

Lot/Batch Number

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Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Ullmann reaction in tetraethyl orthosilicate: a novel synthesis of triarylamines and diaryl ethers
Zhao Y, et al.
Chemical Communications (Cambridge, England), 30(449), 3186-3188 (2007)
Silica xerogels as pharmaceutical drug carriers
Quintanar-Guerrero D, et al.
Expert Opinion on Drug Delivery, 5(6), 485-498 (2009)
Preparation of spherical silica particles by Stober process with high concentration of tetra-ethyl-orthosilicate
Wang XD, et al.
Journal of Colloid and Interface Science, 1(341), 23-29 (2010)
Removal of Cu (II) and Fe (II) ions through thin film composite (TFC) with hybrid membrane
Sulaiman NA, et al.
Journal of Engineering Science and Technology, 36-49 (2016)
Reaction of poly (vinyl butyral) with tetraethyl orthosilicate: grafting of siloxane chains and new composites
Annenkov VV, et al.
Polymer International, 53(6), 772-776 (2004)

Questions

1–10 of 12 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the thermal conductivity of TEOS?

    1 answer
    1. Unfortunately, the thermal conductivity of this product is not determined.

      Helpful?

  4. What is the electrical conductivity or resistivity of TEOS

    1 answer
    1. This product is not tested for electrical conductivity. The compound is not expected to be a conductive material. The presence of TEOS in various coatings may impact the conductivity or resistivity of a given target compound, such as a metallic nanoparticle. See the links below to review articles that may be of interest:
      https://www.researchgate.net/figure/Effect-of-the-addition-of-TEOS-on-a-density-b-resistivity-c-residual-magnetic_fig5_371096514
      https://link.springer.com/article/10.1007/s12633-019-00180-y

      Helpful?

  5. According to the theise, TEOS was used in units of g. Do you sell powder or solid TEOS?

    1 answer
    1. Tetraethyl orthosilicate is only available in the liquid state. The melting point of the pure compound is -82.5 °C. The density of this material is 0.933 g/mL.
      See the link below to review the PubChem profile.
      https://pubchem.ncbi.nlm.nih.gov/compound/Tetraethyl-orthosilicate#section=Melting-Point

      Helpful?

  6. What type of applications can Product No. 86578, Tetraethyl orthosilicate (TEOS), be used in?

    1 answer
    1. TEOS can be used to synthesize sol-gels or aerogels.

      Helpful?

  7. How do you create a sol-gel with Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. TEOS can be polymerized with water; the polymerization is based on the hydrolysis or the Si-O-Et groups through forming networks linked by Si-O-Si groups.

      Helpful?

  8. How does the storage temperature relate to shipping conditions?

    1 answer
    1. The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment.

      Helpful?

  9. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  10. What are the applications of sol-gels formed from Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. One of the most improtant application of the sol-gel process is the snythesis of zeolites. Other applications are optical ceramic materials or functionalized biosensors.

      Helpful?

1–10 of 12 Questions  

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