465348
2-Mercaptophenol
95%
Sinónimos:
2-Hydroxythiophenol
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About This Item
Productos recomendados
Quality Level
assay
95%
refractive index
n20/D 1.6060 (lit.)
density
1.255 g/mL at 25 °C (lit.)
SMILES string
Oc1ccccc1S
InChI
1S/C6H6OS/c7-5-3-1-2-4-6(5)8/h1-4,7-8H
InChI key
VMKYTRPNOVFCGZ-UHFFFAOYSA-N
General description
2-Mercaptophenol (H2mp) is a 1,2-bidentate sulfur containing ligand. It exhibits versatile coordination modes in its ligation to the transition metal atoms.
Application
2-Mercaptophenol may be employed as a complexing agent for the microwave-assisted extraction (MAE) of mercury species from sediments and zoobenthos samples. It may be used for the synthesis of Vanadium (IV) complexes having mixed O, S donor ligands.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Corr. 1B
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk_germany
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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A high-pressure microwave digestion was applied for microwave-assisted extraction (MAE) of mercury species from sediments and zoobenthos samples. A mixture containing 3molL(-1) HCl, 50% aqueous methanol and 0.2molL(-1) citric acid (for masking co-extracted Fe(3+)) was selected as the most suitable
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Reaction of VO(acac)(2) with 2-mercaptophenol (mpH(2)) in the presence of triethylamine gives the mononuclear tris complex (Et(3)NH)(2)[V(mp)(3)] (1), in which the vanadyl oxygen has been displaced. An analogous reaction using 2-mercapto-4-methylphenol (mmpH(2)) afforded (Et(3)NH)(PNP)[V(mmp)(3)] (2), which was structurally characterized. 2
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Early T-cell precursor leukaemia (ETP-ALL) is a high-risk subtype of human leukaemia that is poorly understood at the molecular level. Here we report translocations targeting the zinc finger E-box-binding transcription factor ZEB2 as a recurrent genetic lesion in immature/ETP-ALL. Using
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