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Documentos

459798

Sigma-Aldrich

Allyl alcohol

≥98.5%

Sinónimos:

2-Propen-1-ol

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About This Item

Fórmula lineal:
CH2=CHCH2OH
Número de CAS:
107-18-6
Peso molecular:
58.08
Beilstein/REAXYS Number:
605307
EC Number:
203-470-7
MDL number:
MFCD00002920
UNSPSC Code:
12352200
PubChem Substance ID:
24869598
NACRES:
NA.21

vapor density

2 (vs air)

Quality Level

200

vapor pressure

23.8 mmHg ( 25 °C)

assay

≥98.5%

autoignition temp.

712 °F

expl. lim.

18 %

refractive index

n20/D 1.412 (lit.)

bp

96-98 °C (lit.)

mp

−129 °C (lit.)

density

0.854 g/mL at 25 °C (lit.)

SMILES string

OCC=C

InChI

1S/C3H6O/c1-2-3-4/h2,4H,1,3H2

InChI key

XXROGKLTLUQVRX-UHFFFAOYSA-N

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Application

Used to induce a mouse model of liver damage that has been used to study the mechanisms of hepatotoxicity and hepatic stem cell-mediated repair.

Packaging

View returnable container options.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

71.6 °F - closed cup

flash_point_c

22 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

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Deoxydehydration of glycerol to allyl alcohol catalyzed by rhenium derivatives.
Canale V, et al.
Catalysis Science & Technology, 4(10), 3697-3704 (2014)
Hydrosilylation of allyl alcohol with [HSiMe2OSiO1.5]8: octa (3-hydroxypropyldimethylsiloxy) octasilsesquioxane and its octamethacrylate derivative as potential precursors to hybrid nanocomposites.
Zhang C and Laine RM.
Journal of the American Chemical Society, 122(29), 6979-6988 (2000)
James Y Hamilton et al.
Journal of the American Chemical Society, 135(3), 994-997 (2012-12-22)
The first example of Ir-catalyzed asymmetric substitution reaction with vinyl trifluoroborates is described. The direct reaction between branched, racemic allylic alcohols and potassium alkenyltrifluoroborates proceeded with high site selectivity and excellent enantioselectivity (up to 99%) mediated by an Ir-(P,olefin) complex.
Johanna M Larsson et al.
Journal of the American Chemical Society, 135(1), 443-455 (2012-12-04)
The mechanism of the palladium-catalyzed synthesis of allylic silanes and boronates from allylic alcohols was investigated. (1)H, (29)Si, (19)F, and (11)B NMR spectroscopy was used to reveal key intermediates and byproducts of the silylation reaction. The tetrafluoroborate counterion of the
Synthesis of highly substituted tetrahydrofurans by catalytic polar-radical-crossover cycloadditions of alkenes and alkenols.
Jean-Marc M Grandjean et al.
Angewandte Chemie (International ed. in English), 52(14), 3967-3971 (2013-02-27)
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