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262145

Sigma-Aldrich

Perfluorohexyl iodide

99%

Sinónimos:

Tridecafluoro-1-iodohexane, 1-Iodoperfluorohexane, 1-Iodotridecafluorohexane, Tridecafluorohexyl iodide

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About This Item

Fórmula lineal:
CF3(CF2)5I
Número de CAS:
355-43-1
Peso molecular:
445.95
Beilstein/REAXYS Number:
1802118
EC Number:
206-586-6
MDL number:
MFCD00001063
UNSPSC Code:
12352100
PubChem Substance ID:
24855861
NACRES:
NA.22

assay

99%

form

liquid

refractive index

n20/D 1.329 (lit.)

bp

117 °C (lit.)

density

2.063 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)I

InChI

1S/C6F13I/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI key

BULLJMKUVKYZDJ-UHFFFAOYSA-N

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General description

Perfluorohexyl iodide forms 1:1 complexes with a variety of hydrogen-bond acceptors. It has been grafted onto the isocitronellene/propene copolymer by radical reaction yielding a poly(α-olefin) with fluorinated side chains. The radical addition of perfluorohexyl iodide to vinyl acetate, using azo-bis( isobutyronitrile) (AIBN) as an initiator, has been investigated.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

239.0 °F - closed cup

flash_point_c

115 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Rafel Cabot et al.
Chemical communications (Cambridge, England), (15)(15), 2005-2007 (2009-04-01)
Quantitative studies of the 1 : 1 complexes formed between perfluorohexyl iodide and a variety of hydrogen-bond acceptors have been used to probe the relationship between halogen bonding, hydrogen bonding, desolvation and the electrostatics of non-covalent interactions.
Effect of reaction conditions on the radical addition of perfluorohexyl iodide to vinyl acetate.
Napoli M, et al.
Journal of Fluorine Chemistry, 57(1), 219-227 (1992)
Alexander A Marchione et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 286, 143-147 (2017-12-16)
A train of BURBOP universal rotation pulses has been used to generate a spin lock sufficient to observe TOCSY correlations over a 46 kHz
Zirconocene-MAO-catalyzed homo-and copolymerizations of linear asymmetrically substituted dienes with propene: A novel strategy to functional (co) poly (a-olefin) s.
Hackmann M, et al.
Macromolecular Chemistry and Physics, 199(8), 1511-1517 (1998)
Qian S Liu et al.
Environmental science & technology, 51(17), 10173-10183 (2017-07-27)
Per- and polyfluoroalkyl substances (PFASs) are a global concern because of their ubiquitous occurrence and high persistence in human blood, and increasing amounts of unidentified fluorinated compounds are now becoming new exposure issues. This study aims to investigate the structure-related
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