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238600

Sigma-Aldrich

4-Methoxyphenyl isocyanate

99%

Sinónimos:

1-Isocyanato-4-methoxybenzene, 4-Anisyl isocyanate, 4-Isocyanatoanisole, p-Anisyl isocyanate, p-Methoxyphenyl isocyanate

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About This Item

Fórmula lineal:
CH3OC6H4NCO
Número de CAS:
5416-93-3
Peso molecular:
149.15
Beilstein/REAXYS Number:
471920
EC Number:
226-513-1
MDL number:
MFCD00002026
UNSPSC Code:
12352100
PubChem Substance ID:
24854336
NACRES:
NA.22

Quality Level

100

assay

99%

form

liquid

refractive index

n20/D 1.548 (lit.)

bp

106-110 °C/16 mmHg (lit.)

density

1.151 g/mL at 25 °C (lit.)

SMILES string

COc1ccc(cc1)N=C=O

InChI

1S/C8H7NO2/c1-11-8-4-2-7(3-5-8)9-6-10/h2-5H,1H3

InChI key

FMDGXCSMDZMDHZ-UHFFFAOYSA-N

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General description

Cyclotrimerization of 4-methoxyphenyl isocyanate by CO2-protected N-heterocyclic carbenes based on tetrahydropyrimidin-2-ylidenes has been reported.

Application

4-Methoxyphenyl isocyanate has been used in the preparation of:
  • 6H-indolo[2,3-b]quinolines
  • 1-[2-(2-furyl)-8-methyl-9-substituted-8H-pyrazolo[4,3-e]-1,2,4-triazolo[1,5-c] pyrimidin-5-yl]-3-(4-methoxyphenyl)urea

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Geng Li et al.
Chirality, 27(8), 518-522 (2015-06-04)
Ten novel xylan bisphenylcarbamate derivatives bearing meta- and para-substituents on their phenyl groups were synthesized and their chiral recognition abilities were evaluated as the chiral stationary phases (CSPs) for high-performance liquid chromatography (HPLC) after coating them on macroporous silica. The
Chongsheng Shi et al.
The Journal of organic chemistry, 64(3), 925-932 (2001-10-25)
Thermolysis of the carbodiimide 9a in gamma-terpinene at 138 degrees C produced 2-(phenylamino)quinoline (11a, 49%) and the parent 6H-indolo[2,3-b]quinoline (14a, 16%). Apparently, 11a was produced via the biradical 10a followed by hydrogen-atom abstraction from gamma-terpinene. A two-step biradical pathway through
Pier Giovanni Baraldi et al.
Journal of medicinal chemistry, 46(7), 1229-1241 (2003-03-21)
In the past few years, our group has been involved in the development of A(2A) and A(3) adenosine receptor antagonists which led to the synthesis of SCH58261 (5-amino-7-(2-phenylethyl)-2-(2-furyl)pyrazolo[4,3-e]-1,2,4-triazolo[1,5-c]pyrimidine, 61), potent and very selective at the A(2A) receptor subtype, and N(8)-substituted-pyrazolo[4,3-e]-1,2,4-triazolo[1,5-c]pyrimidines-N(5)-urea
Bhasker Bantu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(13), 3103-3109 (2009-02-13)
Catalytic rivals: Both CO(2)-protected tetrahydropyrimidin-2-ylidene-based N-heterocyclic carbenes (NHCs) and Sn(II)-1,3-dimesitylimidazol-2-ylidene, as well as Sn(II)-1,3-dimesitylimidazolin-2-ylidene complexes (example displayed), have been identified as truly latent catalysts for polyurethane (PUR) synthesis rivaling all existing systems both in activity and latency.A series of CO(2)-protected

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