224448

Phenylmagnesium chloride solution

2.0 M in THF

• Sinónimos: Chlorophenylmagnesium
• Fórmula lineal: C₆H₅MgCl
• Número de CAS: 100-59-4
• Peso molecular: 136.86
• Beilstein/REAXYS Number: 3587900
• MDL number: MFCD00000464
• UNSPSC Code: 12352103
• PubChem Substance ID: 24853438
• NACRES: NA.22

Propiedades

• Quality Level: 200
• reaction suitability: reaction type: Grignard Reaction
• concentration: 2.0 M in THF
• density: ~1.02 g/mL at 20 °C; 1.042 g/mL at 25 °C
• SMILES string: Cl[Mg]c1ccccc1
• InChI: 1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
• InChI key: GQONLASZRVFGHI-UHFFFAOYSA-M

Descripción

Application

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (−)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl₃) in the rechargeable magnesium batteries.

Packaging

View returnable container options.

Other Notes

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid

Información de seguridad

• pictograms: GHS02,GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H314,H335,H336,H351
• pcodes: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 1.4 °F - closed cup
• flash_point_c: -17 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter