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130850

Sigma-Aldrich

3-Butyn-1-ol

97%

Sinónimos:

3-Butynol

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About This Item

Fórmula lineal:
HC≡CCH2CH2OH
Número de CAS:
927-74-2
Peso molecular:
70.09
Beilstein/REAXYS Number:
773710
EC Number:
213-161-9
MDL number:
MFCD00002955
UNSPSC Code:
12352100
eCl@ss:
39020335
PubChem Substance ID:
24847980
NACRES:
NA.22

Quality Level

200

assay

97%

form

liquid

refractive index

n20/D 1.441 (lit.)

bp

128.9 °C (lit.)

mp

−63.6 °C (lit.)

density

0.926 g/mL at 25 °C (lit.)

SMILES string

OCCC#C

InChI

1S/C4H6O/c1-2-3-4-5/h1,5H,3-4H2

InChI key

OTJZCIYGRUNXTP-UHFFFAOYSA-N

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General description

The enthalpies of combustion and vaporization of 3-butyn-1-ol is measured by static bomb combustion calorimetry and correlation gas chromatography techniques.

Application

3-Butyn-1-ol was used to prepare Markovnikov addition product.
Alkynyl substrate used in a study of a palladium-catalyzed coupling with β-tetrionic acid bromide leading to alkynyl substituted furanones in good yield.
Synthon for preparation of oxygen-containing heterocycles and protected esters of s-Hydroxy-L-isoleucine

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

96.8 °F - closed cup

flash_point_c

36 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

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Kopf, Henning; Pietraszuk. et al.
Organometallics, 25(10), 2533-2546 (2006)
Tetrahedron Letters, 48, 105-105 (2007)
Sumod A Pullarkat et al.
Inorganic chemistry, 45(18), 7455-7463 (2006-08-29)
Alcohol functionalized diphosphine ligands with chirality residing on the carbon backbone were prepared using a novel two-stage asymmetric synthetic methodology from the corresponding terminal alkynols. Under mild conditions, the alkynols, 3-butyn-1-ol and 2-propyn-1-ol, were subjected to direct hydrophosphination to give
Deniz Dogruer et al.
Bioorganic & medicinal chemistry letters, 14(2), 523-526 (2003-12-31)
The binding of a series pyridylbutynylamines 6 was examined at alpha4beta2 nACh receptors. Structural modifications, comparing 6 with pyridyl ethers 2, did not consistently result in parallel effects on receptor affinity, suggesting possible differences in their modes of binding. Furthermore
Ederley Vélez et al.
The journal of physical chemistry. A, 109(34), 7832-7838 (2006-07-13)
The enthalpies of combustion and vaporization of 3-buten-1-ol and 3-butyn-1-ol have been measured by static bomb combustion calorimetry and correlation gas chromatography techniques, respectively, and the gas-phase enthalpies of formation, Delta(f)H degrees (m)(g), have been determined, the values being -147.3
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