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Merck

129623

Sigma-Aldrich

2-Mercaptopyrimidine

98%

Sinónimos:

2-Pyrimidinethiol

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About This Item

Fórmula empírica (notación de Hill):
C4H4N2S
Número de CAS:
Peso molecular:
112.15
Beilstein/REAXYS Number:
107105
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

form

powder

mp

230 °C (dec.) (lit.)

SMILES string

Sc1ncccn1

InChI

1S/C4H4N2S/c7-4-5-2-1-3-6-4/h1-3H,(H,5,6,7)

InChI key

HBCQSNAFLVXVAY-UHFFFAOYSA-N

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Application

2-Pyrimidinethiol has been used to study the highly selective palladium catalyzed kinetic resolutions of the racemic cyclic allylic carbonates and racemic acyclic allylic carbonates. It has also been used to study the photodegradation of 2-pyrimidinethiol in aerated aqueous solution using zinc oxide.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Jie Huang et al.
Nanoscale, 2(12), 2733-2738 (2010-10-12)
In this paper, we describe the formation of Au nanoparticle-graphene oxide (Au-GO) and -reduced GO (Au-rGO) composites by noncovalent attachment of Au nanoparticles premodified with 2-mercaptopyridine to GO and rGO sheets, respectively, viaπ-π stacking and other molecular interactions. Compared with
V Sood et al.
Folia morphologica, 37(4), 402-406 (1989-01-01)
The telotrophic ovary of Epilachna vigintioctopunctata is composed of 32-40 ovarioles, each with an apical germarium and a basal vitellarium. The germarium encloses mononucleate and binucleate trophocytes, prefollicular tissue and oogonia, while the vitellarium contains 2-5 oocytes arranged in order
Denis Lima Guerra et al.
Journal of hazardous materials, 166(2-3), 1550-1555 (2009-01-22)
The compound 2-mercaptopyrimidine (MPY) was attached onto synthetic Na-Magadiite (M) and Na-Kanemite (K) samples by homogeneous route. The final matrices named M(MPY) and K(MPY) have been characterized through X-ray powder diffraction and scanning electron microscopy (SEM). The resulted materials were
Maria Carolina P Lima et al.
The journal of physical chemistry. A, 110(22), 7253-7261 (2006-06-02)
A combined Monte Carlo and quantum mechanical study was carried out to analyze the tautomeric equilibrium of 2-mercaptopyrimidine in the gas phase and in aqueous solution. Second- and fourth-order Møller-Plesset perturbation theory calculations indicate that in the gas phase thiol
V Krishnakumar et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 63(2), 454-463 (2005-07-02)
The molecular vibrations of 2-mercapto pyrimidine (MP) and 2,4-diamino-6-hydroxy-5-nitroso pyrimidine (DAHNP) were investigated in polycrystalline sample, at room temperature, by Fourier transform infrared (FT-IR) and FT-Raman spectroscopics. In parallel, ab initio and various density functional (DFT) methods were used to

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