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210021

Sigma-Aldrich

Hydriodic acid

57 wt. % in H2O, distilled, stabilized, 99.95%

Synonym(s):

Hydriotic acid

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About This Item

Empirical Formula (Hill Notation):
HI
CAS Number:
10034-85-2
Molecular Weight:
127.91
MDL number:
MFCD00011347
UNSPSC Code:
12352106
PubChem Substance ID:
329752070
NACRES:
NA.21

Quality Level

100

Assay

99.95%

form

liquid

contains

<1.5% hypophosphorous acid as stabilizer

concentration

57 wt. % in H2O

bp

127 °C (lit.)

density

1.701 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

I

InChI

1S/HI/h1H

InChI key

XMBWDFGMSWQBCA-UHFFFAOYSA-N

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General description

Hydriodic acid (HI) along with red phosphorus (HI/red P) plays the role of a reducing agent for the preparation of methamphetamine. HI/Phosphorous causes the reduction of various polycyclic quinones. HI also participates as a reducing agent for the conversion of various polyarene quinones, hydroquinones and phenols to the corresponding aromatic hydrocarbons.
Hydriodic acid is hydrogen iodide gas dissolved in water. It is a strong acid generally used as a reducing agent.

Application

Hydriodic acid may be used as a reagent for the conversion of fatty alcohols and glyceryl ethers to alkyl iodides.

Pictograms

CorrosionEnvironment
GHS05,GHS09

Signal Word

Danger

Hazard Statements

H290,H314,H411

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Studies on the composition of glyceryl ethers and their preparation from diacyl glyceryl ethers in liver oils.
Guyer KE, et al.
Journal of Lipid Research, 4(4), 385-391 (1963)
Chao Chen et al.
Nature communications, 10(1), 1927-1927 (2019-04-28)
Circularly polarized light (CPL) detection is required in various fields such as drug screening, security surveillance and quantum optics. Conventionally, CPL photodetector needs the installation of optical elements, imposing difficulties for integrated and flexible devices. The established CPL detectors without
Efficient reduction of polycyclic quinones, hydroquinones, and phenols with hydriodic acid.
Konieczny M and Harvey RG.
The Journal of Organic Chemistry, 44(26), 4813-4816 (1979)
Methamphetamine synthesis via hydriodic acid/red phosphorus reduction of ephedrine.
Skinner HF.
Forensic Science International, 48(2), 123-134 (1990)
Daniel J Weisenberger et al.
Cancer epidemiology, biomarkers & prevention : a publication of the American Association for Cancer Research, cosponsored by the American Society of Preventive Oncology, 24(3), 512-519 (2015-01-15)
The CpG island methylator phenotype (CIMP) represents a subset of colorectal cancers characterized by widespread aberrant DNA hypermethylation at select CpG islands. The risk factors and environmental exposures contributing to etiologic heterogeneity between CIMP and non-CIMP tumors are not known.
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