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45687

Supelco

Thiobencarb

PESTANAL®, analytical standard

Synonym(s):

Benthiocarb

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About This Item

Empirical Formula (Hill Notation):
C12H16ClNOS
CAS Number:
28249-77-6
Molecular Weight:
257.78
Beilstein:
1968440
EC Number:
248-924-5
MDL number:
MFCD00055475
UNSPSC Code:
41116107
PubChem Substance ID:
329756900
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CCN(CC)C(=O)SCc1ccc(Cl)cc1

InChI

1S/C12H16ClNOS/c1-3-14(4-2)12(15)16-9-10-5-7-11(13)8-6-10/h5-8H,3-4,9H2,1-2H3

InChI key

QHTQREMOGMZHJV-UHFFFAOYSA-N

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General description

Thiobencarb is a thiocarbamate herbicide, widely used for the control of pests in rice fields.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Thiobencarb may be used as a reference standard for the determination of thiobencarb residues in fruits and vegetables by matrix solid-phase dispersion and liquid chromatography coupled with mass spectrometry.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H410

Precautionary Statements

P273 - P301 + P312 + P330

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ8997
BCBZ3684
SZB8325XV
SZE8325X
8325X

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E Sancho et al.
Ecotoxicology and environmental safety, 56(3), 434-441 (2003-10-25)
European eels (Anguilla anguilla) were exposed to a sublethal thiobencarb concentration of 0.22 mg/L in a flow-through system for 96 h. Mg(2+) and Na(+)-K(+) adenosine triphosphatase (ATPase) activities were evaluated in gill and muscle tissues at 2, 12, 24, 48
Determination of carbamate residues in fruits and vegetables by matrix solid-phase dispersion and liquid chromatography--mass spectrometry.
Fernandez M, et al.
Journal of Chromatography A, 871(1-2), 43-56 (2000)
Kara R Schmelzer et al.
Pest management science, 61(1), 68-74 (2004-12-14)
The herbicide thiobencarb is suspected of causing delayed phytotoxicity syndrome (DPS) in rice plants. While the ultimate agent appears to be its dechlorinated product (deschlorothiobencarb), the influence of organic carbon on the formation of deschlorothiobencarb in California rice field soils
Jianrong Xia
Chemosphere, 59(4), 561-566 (2005-03-25)
Effects of thiobencarb on growth, photosynthesis and photoinhibition of Nostoc sphaeroides colonies were examined. Thiobencarb concentrations higher than 2 mg/l led to a significant decrease in phycoerythrin, phycocyanin and allophycocyanin content, but no significant effect on chlorophyll a (chl a)
Bülent Kaya et al.
Mutation research, 557(1), 53-62 (2004-01-07)
In the present study, the herbicides bentazone, molinate, thiobencarb and trifluralin were evaluated for mutagenic and recombinagenic effects using the wing spot test of Drosophila melanogaster (somatic mutation and recombination test, SMART). Both standard (ST) and high-bioactivation (HB) fly crosses
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