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P73005

Sigma-Aldrich

Pyromellitic diimide

97%

Synonym(s):

Benzene-1,2,4,5-tetracarboxylic diimide, Reillex® 402

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About This Item

Empirical Formula (Hill Notation):
C10H4N2O4
CAS Number:
2550-73-4
Molecular Weight:
216.15
Beilstein:
214780
EC Number:
219-852-1
MDL number:
MFCD00005004
UNSPSC Code:
12352100
PubChem Substance ID:
24898838
NACRES:
NA.22

Assay

97%

form

powder

mp

>320 °C (lit.)

SMILES string

O=C1NC(=O)c2cc3C(=O)NC(=O)c3cc12

InChI

1S/C10H4N2O4/c13-7-3-1-4-6(10(16)12-8(4)14)2-5(3)9(15)11-7/h1-2H,(H,11,13,15)(H,12,14,16)

InChI key

UGQZLDXDWSPAOM-UHFFFAOYSA-N

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Legal Information

Reillex is a registered trademark of Vertellus Specialties, Inc.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000290149
0000214560
0000214561
0000212054
0000211285

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Shin-ichiro Kato et al.
The Journal of organic chemistry, 71(13), 4723-4733 (2006-06-17)
This paper reports the electroscopic and electrochemical properties of [2 + 2] pyromellitic diimide-based cyclophane 1 as well as acyclic N,N'-bis(2-methoxybenzyl)pyromellitic diimide 2 and the clathrate compounds formed by 1. Compound 1 was synthesized by direct cyclocondensation. Its structure was
Bijitha Balan et al.
Organic letters, 9(14), 2709-2712 (2007-06-07)
Complex formation of pyromellitic diimide derivatives with beta-cyclodextrin and anthracene-appended beta-cyclodextrin was studied with use of induced circular dichroism and 1H NMR spectroscopies. It is revealed that pyromellitic diimides form rim-binding type complexes with beta-CD and in these complexes the
Igor V Rubtsov et al.
Journal of the American Chemical Society, 126(9), 2684-2685 (2004-03-05)
We demonstrate for the first time the utility of time-resolved visible pump/mid-infrared (IR) probe spectroscopy to interrogate directly, and provide unique infomation regarding, conformationally dependent photoinduced ET dynamics and the subsequent structural evolution of the resulting charge-separated (CS) state. Exemplary
Hairong Zhang et al.
Chemical communications (Cambridge, England), 46(11), 1917-1919 (2010-03-04)
Nanowires from deposition of pyromellitic diimide (PMDI) from the gas phase and their unique excitation-wavelength-dependent photoluminescence were demonstrated. The luminescence peaks of the PMDI nanowires red-shifted as the excitation wavelength increased. The relationship between the luminescence peak and the excitation
Meisa S Khoshbin et al.
Chemistry, an Asian journal, 1(5), 686-692 (2007-04-19)
Pyromellitic diimide and naphthalene diimide moieties were incorporated into hemilabile phosphanylalkyl thioether ligands. These ligands reacted with [Cu(CH3CN)4]PF6 and [Rh(NBD)Cl]2 (NBD = norbornadiene) by the weak-link approach to form condensed intermediates. Upon reaction of each diimide ligand with these transition-metal
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