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926183

Sigma-Aldrich

Ru-MACHO®-BH

Takasago

Synonym(s):

(OC-6-13)-Carbonyl[2-(diphenylphosphino-κP)-N-[2-(diphenylphosphino-κP)ethyl]ethanamine-κN][tetrahydroborato(1-)-κH]ruthenium

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About This Item

Empirical Formula (Hill Notation):
C29H34BNOP2Ru
CAS Number:
Molecular Weight:
586.41
UNSPSC Code:
12161600
NACRES:
NA.22

Quality Level

form

powder

Application

Ru-MACHO®-BH novel ruthenium catalyst for homogeneous hydrogenations of esters under base free conditions.

Legal Information

Product of Takasago. For research and development purposes only. PCT/JP2010-004301
Ru-MACHO is a registered trademark of Takasago Intl. Corp.

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Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Catalytic Hydrogenation of Esters. Development of an Efficient Catalyst and Processes for Synthesising (R)-1,2-Propanediol and 2-(l-Menthoxy)ethanol
Kuriyama W., et al.
Organic Process Research & Development, 16, 166?171-166?171 (2011)

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