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905925

Sigma-Aldrich

[Pd(terpy)(2-Cl-phen)](BF4)2

≥95%

Synonym(s):

Ritter fluorination catalyst

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About This Item

Empirical Formula (Hill Notation):
C27H18B2ClF8N5Pd
CAS Number:
2133345-76-1
Molecular Weight:
727.95
UNSPSC Code:
12161600
NACRES:
NA.22

Assay

≥95%

form

powder or crystals

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

>300 °C

storage temp.

2-8°C

SMILES string

ClC(C=C1)=NC2=C1C=CC3=CC=C[N]([Pd]45[N]6=C(C7=CC=CC=[N]75)C=CC=C6C8=CC=CC=[N]84)=C32

Application

[Pd(terpy)(2-Cl-phen)](BF4)2 was developed in the Ritter lab for the elecrophilic fluorination of arenes.
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Other Notes

Palladium-catalysed electrophilic aromatic C-H fluorination

Legal Information

This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH (US Patent Pending 16/083,160 and PCT/US2017/021563).

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Kumiko Yamamoto et al.
Nature, 554(7693), 511-514 (2018-02-23)
Aryl fluorides are widely used in the pharmaceutical and agrochemical industries, and recent advances have enabled their synthesis through the conversion of various functional groups. However, there is a lack of general methods for direct aromatic carbon-hydrogen (C-H) fluorination. Conventional

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