900942
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II)
≥95%
Synonym(s):
SK-J004-1n
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About This Item
Empirical Formula (Hill Notation):
C43H48ClFeNNiP2
CAS Number:
Molecular Weight:
790.79
UNSPSC Code:
12352103
NACRES:
NA.22
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Quality Level
Assay
≥95%
form
powder or solid
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
SMILES string
C[Ni+]C1=CC=C(C#N)C=C1.[C]2(CP(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]
Application
Amination of aryl chlorides with ammonium salts.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Find documentation for the products that you have recently purchased in the Document Library.
Ni?Catalyzed Amination Reactions: An Overview.
Marin M, et al.
Chemical Record, 16(4), 1819-1832 (2016)
Nickel?Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts.
Green R A and Hartwig J F
Angewandte Chemie (International Edition in English), 54(12), 3768-3772 (2015)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Sarah Z Tasker et al.
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.
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