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900168

Sigma-Aldrich

Lead(II) iodide

99.999% trace metals basis, perovskite grade

Synonym(s):

Lead diiodide

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About This Item

Linear Formula:
PbI2
CAS Number:
10101-63-0
Molecular Weight:
461.01
EC Number:
233-256-9
MDL number:
MFCD00011163
UNSPSC Code:
12352302
PubChem Substance ID:
329769784
NACRES:
NA.23

description

Powder or beads

Quality Level

100

Assay

99.999% trace metals basis

form

beads

bp

954 °C (lit.)

mp

402 °C (lit.)

density

6.16 g/mL at 25 °C (lit.)

SMILES string

I[PbH2]I

InChI

1S/2HI.Pb/h2*1H;/q;;+2/p-2

InChI key

RQQRAHKHDFPBMC-UHFFFAOYSA-L

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General description

Lead(II)iodide is a wide bandgap (2.32 eV) semiconductor material. It has uniqueproperties like high resistivity, chemical stability, and a wide range oftemperature applications (−200 °C up to +130 °C). Perovskites with lead as the central cation produce the bestphotovoltaic efficiency. We offer lead iodide, specifically designed forenhanced solar cell performance.

Application

Lead iodide finds application in synthesis of perovskites based photovoltaic materials. Our perovskite grade PbI2 can readily be dissolved in DMF to yield 1M solution.
Lead(II) iodide (PbI2) in perovskite grade refers to high-purity lead iodide specifically used for the synthesis and fabrication of perovskite materials, such as formamidinium lead iodide (FAPbI3) or methylammonium lead iodide(MAPbI3), which are commonly studied for perovskite solar cells and other optoelectronic devices. The high purity of lead(II) iodide perovskite grade contributes to the efficiency, stability and reproducibility of perovskite solar cells.

Other Notes

Very air and moisture sensitive. Please handle under argon atmosphere in a glove box.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
0000390435
0000390443
0000390071
0000370728
0000358004

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Gratzel M, et al.
Advances in Functional Materials, 25, 6936-6936 (2015)
Samuel D Stranks et al.
Nature nanotechnology, 10(5), 391-402 (2015-05-08)
Metal-halide perovskites are crystalline materials originally developed out of scientific curiosity. Unexpectedly, solar cells incorporating these perovskites are rapidly emerging as serious contenders to rival the leading photovoltaic technologies. Power conversion efficiencies have jumped from 3% to over 20% in

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