713031
1-Ethyl-3-methylimidazolium iodide
97%
Synonym(s):
EMIMI
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About This Item
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Quality Level
Assay
≥96.5% (HPLC)
97%
form
powder
impurities
≤0.5% water
SMILES string
[I-].CCn1cc[n+](C)c1
InChI
1S/C6H11N2.HI/c1-3-8-5-4-7(2)6-8;/h4-6H,3H2,1-2H3;1H/q+1;/p-1
InChI key
IKQCDTXBZKMPBB-UHFFFAOYSA-M
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General description
1-Ethyl-3-methylimidazolium iodide is an ionic liquid that can be prepared by reacting methylimidazole with iodoethane. The addition of EMImI to 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF4), increase its capacitance while developing electric double-layer capacitors (EDLCs) based on EMImBF4.
Application
EMImI reacts with aluminum chloride to form 1-ethyl-3-methylimidazolium halogenoaluminate ionic liquid, [emim]I–(AlCl3)x, which is an excellent solvent for Friedel–Crafts acylation of ferrocene.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Electrochemical characteristics pyrolytic graphite| mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and 1-ethyl-3-methylimidazolium iodide interface
Journal of Electroanalytical Chemistry, 719, 133-137 (2014)
1-Ethyl-3-methylimidazolium halogenoaluminate ionic liquids as solvents for Friedel-Crafts acylation reactions of ferrocene.
J. Chem. Soc., Dalton Trans., 1, 63-66 (1999)
Evidence for hydrogen bonding in solutions of 1-ethyl-3-methylimidazolium halides, and its implications for room-temperature halogenoaluminate (III) ionic liquids
J. Chem. Soc., Dalton Trans., 23, 3405-3413 (1994)
Mass and Charge Transport in the Polymer?Ionic-Liquid System PEO?EMImI: From Ionic-Liquid-in-Polymer to Polymer-in-Ionic-Liquid Electrolytes
The Journal of Physical Chemistry B, 119.17, 5693-5700 (2015)
The electrochemical characteristics of the mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and 1-ethyl-3-methylimidazolium iodide
Journal of Electroanalytical Chemistry, 730, 59-64 (2014)
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